Grafting-from polymerization inside a polyelectrolyte hollow-capsule microreactor

被引:45
作者
Choi, WS [1 ]
Park, JH [1 ]
Koo, HY [1 ]
Kim, JY [1 ]
Cho, BK [1 ]
Kim, DY [1 ]
机构
[1] Gwangju Inst Sci & Technol, Ctr Frontier Mat, Dept Mat Sci & Engn, Kwangju 500712, South Korea
关键词
materials science; microreactors; polyelectrolytes polymerization;
D O I
10.1002/anie.200460971
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Interior decorating: Polymerization of styrene sulfonate monomers on the inner surface of polyelectrolyte hollow capsules results in polymers having molecular weights an order of magnitude higher than those produced in solution. The shape of the capsules after polymerization can be manipulated by varying the styrene sulfonate content (see SEM images; a: 25 wt%, b: 40 wt%). © 2005 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:1096 / 1101
页数:6
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