Effects of cation and anion on physical properties of room-temperature ionic liquids

被引：124

作者：

Seki, Shiro ^{[1
]}

Kobayashi, Takeshi ^{[1
]}

Kobayashi, Yo ^{[1
]}

Takei, Katsuhito ^{[1
]}

Miyashiro, Hajime ^{[1
]}

Hayamizu, Kikuko ^{[2
]}

Tsuzuki, Seiji ^{[2
]}

Mitsugi, Takushi ^{[3
]}

Umebayashi, Yasuhiro ^{[3
]}

机构：

[1] CRIEPI, Mat Sci Res Lab, Tokyo 2018511, Japan

[2] Natl Inst Adv Ind Sci & Technol, Tsukuba, Ibaraki 3058565, Japan

[3] Kyushu Univ, Dept Chem, Fac Sci, Higashi Ku, Fukuoka 8128581, Japan

来源：

JOURNAL OF MOLECULAR LIQUIDS | 2010年 / 152卷 / 1-3期

关键词：

Room-temperature ionic liquid; Viscosity; Density; Temperature dependence; Molecular design; MOLECULAR-DYNAMICS SIMULATIONS; ELECTROCHEMICAL PROPERTIES; PHYSICOCHEMICAL PROPERTIES; VOLUMETRIC PROPERTIES; ELECTROLYTES; VISCOSITY; COEFFICIENTS; BASE;

D O I：

10.1016/j.molliq.2009.10.008

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

To investigate the effects of the cation and anion on the physical properties of room-temperature ionic liquids, the temperature dependences of the viscosity and density of 12 (7 cationic, 6 anionic) room-temperature ionic liquids were measured and analyzed The effects of the cation were investigated using chainlike and cyclic (aromatic and non-aromatic) nitrogen-based room-temperature ionic liquids, and amide-type (N(SO(2)C(x)F(2x+1))(2), x=0, 1,2) anions and anions of various shapes were used to investigate the effects of the anion (C) 2009 Elsevier B V All rights reserved

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页码：9 / 13

页数：5

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