Palladium based membranes and membrane reactors for hydrogen production and purification: An overview of research activities at Tecnalia and TU/e

被引：70

作者：

Fernandez, E. ^{[1
,2
]}

Helmi, A. ^{[2
]}

Medrano, J. A. ^{[2
]}

Coenen, K. ^{[2
]}

Arratibel, A. ^{[1
,2
]}

Melendez, J. ^{[1
,3
]}

de Nooijer, N. C. A. ^{[2
]}

Spallina, V. ^{[2
]}

Viviente, J. L. ^{[1
]}

Zuniga, J. ^{[1
]}

Annaland, M. van Sint ^{[2
]}

Tanaka, D. A. Pacheco ^{[1
]}

Gallucci, F. ^{[2
]}

机构：

[1] TECNALIA, Div Energy & Environm, Mikeletegi Pasealekua 2, San Sebastian 20009, Spain

[2] Eindhoven Univ Technol, Chem Proc Intensificat, Dept Chem Engn & Chem, POB 513, NL-5612 AZ Eindhoven, Netherlands

[3] Univ Basque Country, UPV EHU, Chem Engn & Environm Dept, C Alameda Urquijo S-N, Bilbao 48013, Spain

来源：

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2017年 / 42卷 / 19期

关键词：

Pd-membrane; Membrane reactor; Hydrogen production; Membrane manufacturing scale-up; FLUIDIZED-BED REACTORS; AG SUPPORTED MEMBRANES; PURE H-2 PRODUCTION; CO2; CAPTURE; COMPOSITE MEMBRANES; PD; METHANE; PERFORMANCE; FUEL;

D O I：

10.1016/j.ijhydene.2017.03.067

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In this paper, the main achievements of several European research projects on Pd based membranes and Pd membrane reactors for hydrogen production are reported. Pd-based membranes have received an increasing interest for separation and purification of hydrogen. In addition, the integration of such membranes in membrane reactors has been widely studied for enhancing the efficiency of several dehydrogenation reactions. The integration of reaction and separation in one multifunctional reactor allows obtaining higher conversion degrees, smaller reactor volumes and higher efficiencies compared with conventional systems. In the last decade, much thinner dense Pd-based membranes have been produced that can be used in membrane reactors. However, the thinner the membranes the higher the flux and the higher the effect of concentration polarization in packed bed membrane reactors. A reactor concept that can circumvent (or at least strongly reduce) concentration polarization is the fluidized bed membrane reactor configuration, which improves the heat transfer as well. Tecnalia and TU/e are involved in several European projects that are related to development of fluidized bed membrane reactors for hydrogen production using thin Pd-based (<5 mu m) supported membranes for different application: In DEMCAMER project a water gas shift (WGS) membrane reactor was developed for high purity hydrogen production. ReforCELL aims at developing a high efficient heat and power micro -cogeneration system (m-CHP) using a methane reforming fluidized membrane reactor. The main objective of FERRET is the development of a flexible natural gas membrane reformer directly linked to the fuel processor of the micro-CHP system. FluidCELL aims the Proof-of-Concept of a m-CHP system for decentralized off-grid using a bioethanol reforming membrane reactor. BIONICO aims at applying membrane reactors for biogas conversion to hydrogen. The fluidized bed system allows operating at a virtually uniform temperature which is beneficial in terms of both membrane stability and durability and for the reaction selectivity and yield. (C) 2017 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.

引用

页码：13763 / 13776

页数：14

共 40 条

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