First total synthesis of Mappain with a Prenylated and Gernylated Stilbene

被引：4

作者：

Chakrapani, Lakkoju ^{[1
]}

Jung, Eun Mi ^{[1
]}

Lee, Yong Rok ^{[1
]}

机构：

[1] Yeungnam Univ, Sch Chem Engn & Technol, Kyongsan 712749, South Korea

来源：

HELVETICA CHIMICA ACTA | 2010年 / 93卷 / 05期

关键词：

RESVERATROL OLIGOMERS; OLIGOSTILBENES; PICEATANNOL; ANALOGS; COMPLEX; PLANT;

D O I：

10.1002/hlca.200900318

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first synthesis of naturally occuring mappain has been achieved by a convergent sequence. The key strategy involved in the synthesis of mappain was a (E)-stilbene formation by Horner-Wads-worth-Emmons reation of the corresponding prenylated benzaldehyde with a geranylated benzyl phosphonate.

引用

页码：829 / 836

页数：8

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