N-alkyl ammonium perrhenate salts as catalysts for the epoxidation of olefins under mild conditions

被引：8

作者：

Cokoja, Mirza ^{[1
,2
,3
]}

Reich, Robert M. ^{[2
,3
]}

Kuehn, Fritz E. ^{[2
,3
]}

机构：

[1] Tech Univ Munich, Dept Chem, Lichtenbergstr 4, D-85747 Garching, Germany

[2] Tech Univ Munich, Catalysis Res Ctr, Lichtenbergstr 4, D-85747 Garching, Germany

[3] Tech Univ Munich, Mol Catalysis, Dept Chem, D-85747 Garching, Germany

来源：

CATALYSIS COMMUNICATIONS | 2017年 / 100卷

关键词：

Homogeneous catalysis; Perrhenate; Ionic liquids; Epoxidation; Olefins; Hydrogen peroxide; IONIC LIQUIDS; PHASE;

D O I：

10.1016/j.catcom.2017.06.043

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A series of N-allcylammonium perrhenate salts [N(R-1)(3)R-2](+) [ReO4](-) with varying substituents R-1 and R-2 were synthesized and characterized and used as catalysts for the epoxidation of olefins. The effect of the substitution pattern on the catalytic activity was investigated.

引用

页码：103 / 106

页数：4

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