Electrophilicity and nucleophilicity index for radicals

被引：390
|
作者：
De Vleeschouwer, Freija
Van Speybroeck, Veronique
Waroquier, Michel
Geerlings, Paul
De Proft, Frank
机构：
[1] Vrije Univ Brussel, Eenheid Algemene Chem, ALGC, Fac Wetenschappen, B-1050 Brussels, Belgium
[2] Univ Ghent, CMM, B-9000 Ghent, Belgium
来源：
ORGANIC LETTERS | 2007年 / 9卷 / 14期
关键词：
D O I：
10.1021/ol071038k
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Radicals can be regarded as electrophilic/nucleophilic, depending on their tendency to attack sites of relatively higher/lower electron density. In this paper, an electrophilicity scale, global as well as local, and a nucleophilicity scale for 35 radicals is reported. The global electrophilicity scale correlates well with the nucleophilicity scale, suggesting that these concepts are inversely related.
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页码：2721 / 2724
页数：4
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