Electrophilicity and nucleophilicity index for radicals

被引：439

作者：

De Vleeschouwer, Freija

Van Speybroeck, Veronique

Waroquier, Michel

Geerlings, Paul

De Proft, Frank

机构：

[1] Vrije Univ Brussel, Eenheid Algemene Chem, ALGC, Fac Wetenschappen, B-1050 Brussels, Belgium

[2] Univ Ghent, CMM, B-9000 Ghent, Belgium

来源：

ORGANIC LETTERS | 2007年 / 9卷 / 14期

关键词：

D O I：

10.1021/ol071038k

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Radicals can be regarded as electrophilic/nucleophilic, depending on their tendency to attack sites of relatively higher/lower electron density. In this paper, an electrophilicity scale, global as well as local, and a nucleophilicity scale for 35 radicals is reported. The global electrophilicity scale correlates well with the nucleophilicity scale, suggesting that these concepts are inversely related.

引用

页码：2721 / 2724

页数：4

共 34 条

[1]

BERANEK I, 1989, NATO ADV SCI I C-MAT, V260, P303

[2] Variation of the electrophilicity index along the reaction path [J].