In the absence of a chemical reductant and other protective reagents, noble metal gold hybrid nanoparticles are successfully prepared by Co-60 gamma-ray irradiation using fifth-generation poly(amidoamine) dendrimer with surface amine-terminated group as polymeric template. The zerovalent gold is of spherical structure and the particle size is on nanometer scale range of 3-12 nm. The size distribution of gold nanoparticles displays multidispersity. The results of FTIR show that interactions between dendrimer template and gold nanoparticle exist in intra-molecule and intermolecule of fifth-generation poly(amidoamine) dendrimer. (C) 2006 Elsevier B.V. All rights reserved.
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Univ Michigan, Dept Chem, Ann Arbor, MI 48109 USA
Univ Michigan, Michigan Nanotechnol Inst Med & Biol Sci, Ann Arbor, MI 48109 USAUniv Michigan, Dept Chem, Ann Arbor, MI 48109 USA
van Dongen, Mallory A.
Desai, Ankur
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Univ Michigan, Michigan Nanotechnol Inst Med & Biol Sci, Ann Arbor, MI 48109 USAUniv Michigan, Dept Chem, Ann Arbor, MI 48109 USA
Desai, Ankur
Orr, Bradford G.
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Univ Michigan, Michigan Nanotechnol Inst Med & Biol Sci, Ann Arbor, MI 48109 USA
Univ Michigan, Dept Phys, Ann Arbor, MI 48109 USAUniv Michigan, Dept Chem, Ann Arbor, MI 48109 USA
Orr, Bradford G.
Baker, James R., Jr.
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Univ Michigan, Michigan Nanotechnol Inst Med & Biol Sci, Ann Arbor, MI 48109 USA
Univ Michigan, Dept Internal Med, Ann Arbor, MI 48109 USAUniv Michigan, Dept Chem, Ann Arbor, MI 48109 USA
Baker, James R., Jr.
Holl, Mark M. Banaszak
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Univ Michigan, Dept Chem, Ann Arbor, MI 48109 USA
Univ Michigan, Michigan Nanotechnol Inst Med & Biol Sci, Ann Arbor, MI 48109 USAUniv Michigan, Dept Chem, Ann Arbor, MI 48109 USA