The rheology of recycled EVA/LDPE modified bitumen

被引:45
作者
García-Morales, M
Partal, P
Navarro, FJ
Martínez-Boza, F
Mackley, MR
Gallegos, C
机构
[1] Univ Huelva, Fac Ciencias Expt, Dept Ingn Quim, Huelva 21071, Spain
[2] Univ Cambridge, Dept Chem Engn, Cambridge CB2 3RA, England
关键词
modified bitumen; recycled polymer; flow behaviour; linear viscoelasticity; capillary rheometry;
D O I
10.1007/s00397-004-0385-4
中图分类号
O3 [力学];
学科分类号
08 ; 0801 ;
摘要
This paper describes linear viscoelasticity, at low and intermediate temperatures, and the flow behaviour, at high temperatures, of polymer modified bitumen (PMB) containing 5 and 9 wt% recycled EVA/LDPE. The relationship between flow behaviour and microstructure of the modified bitumen was also considered, by comparison of experiments carried out in capillary and rotational rheometers and photomicrographs taken using a microscopy system whilst the sample was being sheared. Blends of 60/70 penetration grade bitumen and waste plastic (EVA/LDPE) were processed in an open mixer using a four blade propeller. Rheological tests, differential scanning calorimetry (DSC) and microscopy showed that the bitumen performance was improved by adding the recycled polymer. As a consequence, the use of recycled EVA/LDPE in PMBs can be considered a suitable and interesting alternative from both an environmental and economical point of view. The experimental results also show that pure bitumen has shear-thinning characteristics. The blending of polymer into the bitumen modifies the melt processing characteristics of the blend, whilst the viscoelastic properties of the semi-solid composite are enhanced.
引用
收藏
页码:482 / 490
页数:9
相关论文
共 25 条
[1]   Rheological properties of styrene butadiene styrene polymer modified road bitumens [J].
Airey, GD .
FUEL, 2003, 82 (14) :1709-1719
[2]  
Barnes H.A., 1989, An introduction to rheology
[3]   Use of rheological compatibility criteria to study SBS modified asphalts [J].
Becker, MY ;
Müller, AJ ;
Rodriguez, Y .
JOURNAL OF APPLIED POLYMER SCIENCE, 2003, 90 (07) :1772-1782
[4]  
Blanco R, 1996, J APPL POLYM SCI, V61, P1493
[5]   Shifting the bitumen structure from sol to gel [J].
Bonemazzi, F ;
Giavarini, C .
JOURNAL OF PETROLEUM SCIENCE AND ENGINEERING, 1999, 22 (1-3) :17-24
[6]   Flow of non-Newtonian fluids in fixed and fluidised beds [J].
Chhabra, RP ;
Comiti, J ;
Machac, I .
CHEMICAL ENGINEERING SCIENCE, 2001, 56 (01) :1-27
[7]  
CROCKFORD WW, 1995, 13331F TEX A M U TEX
[8]   THE EFFECT OF ENTANGLEMENTS ON THE RHEOLOGICAL BEHAVIOR OF POLYBUTADIENE CRITICAL GELS [J].
DEROSA, ME ;
WINTER, HH .
RHEOLOGICA ACTA, 1994, 33 (03) :220-237
[9]   Blends of bitumen with various polyolefins [J].
Fawcett, AH ;
McNally, T .
POLYMER, 2000, 41 (14) :5315-5326
[10]   Linear viscoelasticity of recycled EVA-modified bitumens [J].
García-Morales, M ;
Partal, P ;
Navarro, FJ ;
Martínez-Boza, F ;
Gallegos, C .
ENERGY & FUELS, 2004, 18 (02) :357-364