Solvothermal synthesis of a layered open-framework chlorocadmium oxalate, Cd2(C2O4)0.5Cl3NaCl•4H2O

被引：35

作者：

Vaidhyanathan, R ^{[1
]}

Natarajan, S ^{[1
]}

Rao, CNR ^{[1
]}

机构：

[1] Jawaharlal Nehru Ctr Adv Sci Res, Chem & Phys Mat Unit, Bangalore 560064, Karnataka, India

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2003年 / 09期

关键词：

materials science; cadmium; solvothermal synthesis; metathesis;

D O I：

10.1002/ejic.200200612

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The metathesis reaction between CdCl2.2H(2)O and sodium oxalate in n-hexanol under solvothermal conditions yields a hybrid compound of formula Cd-2(C2O4)(0.5)Cl3NaCl.4H(2)O, It consists of one-dimensional chains formed by Cd and Cl atoms, containing mu(2)(Cl) and mu(3)(Cl) bridges, and cross-linked by oxalate units to give a layered structure. The Na+ ions and water molecules occupy the interlamellar spaces. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003).

引用

页码：1675 / 1680

页数：6

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