A simple parameter-free wavefunction for the ground state of two-electron atoms

被引:11
作者
Ancarani, L. U. [1 ]
Rodriguez, K. V.
Gasaneo, G.
机构
[1] Univ Paul Verlaine Metz, Lab Phys Mol & Collis, F-57078 Metz, France
[2] Univ Nacl Sur, Dept Fis, RA-8000 Buenos Aires, DF, Argentina
[3] Consejo Nacl Invest Cient & Tecn, RA-8000 Buenos Aires, DF, Argentina
关键词
D O I
10.1088/0953-4075/40/13/013
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
We propose a simple and pedagogical wavefunction for the ground state of two-electron atoms which (i) is parameter free, (ii) satisfies all two-particle cusp conditions, (iii) yields reasonable ground-state energies, including the prediction of a bound state for H-. The mean energy, and other mean physical quantities, is evaluated analytically. The simplicity of the result can be useful as an easy-to-use wavefunction when testing collision models.
引用
收藏
页码:2695 / 2702
页数:8
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