Carbon supports on preparing iron-nitrogen dual-doped carbon (Fe-N/C) electrocatalysts for microbial fuel cells: mini-review

Microbial fuel cells (MFCs) are devices that treat sewage and generate electricity. Recent researches have demonstrated that the characteristics of carbon precursors can tremendously influence the performance of the MFC cathode. Carbon nanomaterials with good crystallinity as well as high specific surface area (e.x., graphene and carbon nanotube) can not only accelerate charge transport but also afford a good dispersion of catalytic active components, leading to high MFC performance. On these bases, the preparation of highly-active Fe-N/C catalysts using different carbon substrates are mainly discussed in this review. It is pointed out that increasing the surface area and conductivity as well as elevating the density of active sites to reduce the oxygen reduction overpotential is still the emphasis of the current works. At present, although the researchers have made some progress, the output power density is far from meeting the actual application needs. (C) 2020 Elsevier Ltd. All rights reserved.