Particulate matter and particle-bound polycyclic aromatic hydrocarbons in the Dapu road tunnel in Shanghai

被引:6
作者
Zhao, Quan [1 ]
Yu, Qi [1 ]
Chen, Limin [1 ]
机构
[1] Fudan Univ, Dept Environm Sci & Engn, Shanghai 200433, Peoples R China
关键词
particulate matter; PAII; size distribution; vehicular emission; tunnel; FINE ORGANIC AEROSOL; SIZE DISTRIBUTIONS; CARCINOGENIC IMPACT; DIESEL VEHICLES; URBAN AEROSOLS; MOBILE SOURCES; EMISSIONS; CARBON; CHINA; GASOLINE;
D O I
10.1504/IJEP.2010.032243
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Airborne Particulate Matter (PM) was collected ill a cross-river road tunnel using portable air samplers and a cascade impactor. Sixteen EPA priority Polycyclic Aromatic Hydrocarbons (PAH) in the PM were quantified by gas chromatography/mass spectrometry. Profiles and diagnostic ratios of PAHs were investigated, and size distribution of PM mass and PAHs were discussed. High concentrations of PM2.5 (2.30 +/- 0.86 mg m(-3)) and total 16 PAHs in PM2.5 (841.7 +/- 116.9 ng m(-3)) were observed. The profiles of individual PAH and diagnostic ratios of Ant/(Ant + Phe), Flt/(Flt + Pyr), BaA/(BaA + Chr), IcdP/(IcdP + BghiP) represented typical emissions from motor vehicles. Size distribution patterns and correlation between mass median aerodynamic diameters and log p(L)(0) reflected the co-influence of vehicular emissions and volatilisation-condensation processes on the size partitioning of PM mass and individual PAHs in the tunnel.
引用
收藏
页码:21 / 37
页数:17
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