Spectroscopy of cyanodiacetylene in solid argon and the photochemical generation of isocyanodiacetylene

被引：32

作者：

Coupeaud, Anne

Turowski, Michal

Gronowski, Marcin

Pietri, Nathalie

Couturier-Tamburelli, Isabelle

Kolos, Robert

Aycard, Jean-Pierre

机构：

[1] Univ Aix Marseille 1, UMR CNRS 6633, Equipe Spectrometries & Dynam Mol, F-13397 Marseille 20, France

[2] Polish Acad Sci, Inst Phys Chem, PL-01224 Warsaw, Poland

来源：

JOURNAL OF CHEMICAL PHYSICS | 2007年 / 126卷 / 16期

关键词：

D O I：

10.1063/1.2720842

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Following the measurements of UV and mid-IR spectra of cyanodiacetylene, H-(CC)(2)-CN, isolated in low temperature Ar matrices, the first photochemical study on this compound and on its H-2 isotopomer was carried out with the laser light tuned to 267 nm and with far-UV discharge lamps. Evidence for the formation of isocyanodiacetylene, H-(CC)(2)-NC, was found in infrared absorption spectra interpreted with the aid of available theoretical predictions. (c) 2007 American Institute of Physics.

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页数：8

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