Copper-Catalyzed Oxidative -Ketoacylations of Sulfoximines with Aryl Methyl Ketones and Dioxygen as Terminal Oxidant

被引：19

作者：

Cheng, Hanchao ^{[1
]}

Bolm, Carsten ^{[1
]}

机构：

[1] Rhein Westfal TH Aachen, Inst Organ Chem, Landoltweg 1, D-52074 Aachen, Germany

来源：

SYNLETT | 2016年 / 27卷 / 05期

关键词：

sulfoximine; ketone; dioxygen; oxidative coupling; -ketoacylation; ALPHA-OXOCARBOXYLIC ACIDS; SOLVENT-FREE CONDITIONS; C BOND-CLEAVAGE; EFFICIENT SYNTHESIS; PROTEASE INHIBITOR; MOLECULAR-OXYGEN; ROOM-TEMPERATURE; METAL-FREE; KETOAMIDES; AMINES;

D O I：

10.1055/s-0035-1560989

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient copper-catalyzed C-H/N-H bond functionalization for the synthesis of -keto-N-acyl sulfoximines from aryl methyl ketones and NH-sulfoximines with molecular oxygen as terminal oxidant has been developed.

引用

页码：769 / 772

页数：4

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