Univalent iron monoazaetioporphyrin complexes studied by Mossbauer spectroscopy

被引：0
|
作者：
Kaczmarzyk, T
Dzilinski, K
Sinyakov, GN
Egorova, GD
机构：
[1] Czestochowa Tech Univ, Inst Phys, PL-42200 Czestochowa, Poland
[2] Belarus Acad Sci, Inst Mol & Atom Phys, Minsk 220072, BELARUS
来源：
NUKLEONIKA | 2003年 / 48卷
关键词：
EPR; iron porphyrins; Mossbauer spectroscopy; reduction reactions;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Results of Mossbauer and EPR studies of univalent-iron monoazaetioporphyrin complexes [Fe(I)(MAEP)] are presented in this paper. Fe(I)(MAEP) were generated using the chemical reduction method. Three forms of the univalent-iron monoazaetioporphyrin complexes were observed: (1) typical Fe(I)(MAEP), (II) with an additional electron on the porphyrin ligand [Fe(I)(MAEP(.))](-) and (III) the Fe(I)(MAEPh) phlorin structure. Electron configuration of Fe(I) ions in these complexes is (d(xy))(2)(d(xz),d(yz))(4)(d(z)(2))(1). The [Fe(I)(MAEP(.))(-) structure is stable only in solution and it is transferred into Fe(l)(MAEP) in the solid state. Mossbauer parameters for all products of the reduction reaction are given.
引用
收藏
页码：S31 / S34
页数：4
相关论文
共 50 条
  • [41] An enthalpy of solution of platinum in iron studied by 57Fe Mossbauer spectroscopy
    Konieczny, Robert
    Idczak, Rafal
    Elsner, Jakub
    Chojcan, Jan
    HYPERFINE INTERACTIONS, 2012, 206 (1-3): : 119 - 124
  • [42] FAST RELAXATION OF POLYCRYSTALLINE FE(III) COMPLEXES STUDIED BY MOSSBAUER-SPECTROSCOPY
    MAGALHAESPANIAGO, R
    PFANNES, HD
    ABRAS, A
    HYPERFINE INTERACTIONS, 1994, 83 (1-4): : 401 - 406
  • [43] MOSSBAUER-SPECTROSCOPY STUDIES OF POLYACETYLENE DOPED WITH IRON CHLORIDE COMPLEXES
    PRON, A
    ZAGORSKA, M
    KUCHARSKI, Z
    LUKASIAK, M
    SUWALSKI, J
    MATERIALS RESEARCH BULLETIN, 1982, 17 (12) : 1505 - 1510
  • [44] Coprecipitation of iron and platinum(IV) hydroxo complexes as probed by Mossbauer spectroscopy
    Pankratov, D. A.
    Kiselev, Yu. M.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2009, 54 (09) : 1451 - 1454
  • [45] Iron complexes by Mossbauer spectroscopy in extracts from Point of Ayr coal
    Herod, AJ
    Gibb, TC
    Herod, AA
    Xu, B
    Zhang, SF
    Kandiyoti, R
    FUEL, 1996, 75 (04) : 437 - 442
  • [46] Mossbauer spectroscopy and electronic structure of bimetallic iron-nitrosyl complexes
    Popescu, Victoria
    Cohara, Morgan
    Ghosh, Pokhraj
    Darensbourg, Marcetta
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2016, 251
  • [47] Processes in geophysics studied by Mossbauer spectroscopy
    Helgason, Ö
    HYPERFINE INTERACTIONS, 2004, 156 (01): : 379 - 388
  • [48] Influence of pH, Iron Source, and Fe/Ligand Ratio on Iron Speciation in Lignosulfonate Complexes Studied Using Mossbauer Spectroscopy. Implications on Their Fertilizer Properties
    Carrasco, Jaime
    Kovacs, Krisztina
    Czech, Viktoria
    Fodor, Ferenc
    Lucena, Juan J.
    Vertes, Attila
    Hernandez-Apaolaza, Lourdes
    JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2012, 60 (13) : 3331 - 3340
  • [49] Iron fluorides assisted dehydrogenation and hydrogenation of MgH2 studied by Mossbauer spectroscopy
    Malka, I. E.
    Blachowski, A.
    Ruebenbauer, K.
    Przewoznik, J.
    Zukrowski, J.
    Czujko, T.
    Bystrzycki, J.
    JOURNAL OF ALLOYS AND COMPOUNDS, 2011, 509 (17) : 5368 - 5372
  • [50] Magnetic behaviour of iron oxychloride and its organometallic intercalation compounds studied by Mossbauer spectroscopy
    Dai, YD
    Han, W
    Zheng, LK
    Xia, YF
    CHINESE PHYSICS LETTERS, 2005, 22 (08) : 2059 - 2062
12345