Transition-Metal-Free and Oxidant-Free Cross-Coupling of Arylhydrazines with Disulfides: Base-Promoted Synthesis of Unsymmetrical Aryl Sulfides

被引：38

作者：

Taniguchi, Toshihide ^{[1
,3
]}

Naka, Takuya ^{[1
]}

Imoto, Mitsutaka ^{[1
]}

Takeda, Motonori ^{[1
]}

Nakai, Takeo ^{[2
]}

Mihara, Masatoshi ^{[2
]}

Mizuno, Takumi ^{[2
]}

Nomoto, Akihiro ^{[3
]}

Ogawa, Akiya ^{[3
]}

机构：

[1] Seika Corp, 1-1-82 Kozaika, Wakayama 6410007, Japan

[2] Osaka Res Inst Ind Sci & Technol, Morinomiya Ctr, Joto Ku, 1-6-50 Morinomiya, Osaka 5368553, Japan

[3] Osaka Prefecture Univ, Grad Sch Engn, Dept Appl Chem, Naka Ku, 1-1 Gakuen Cho, Sakai, Osaka 5998531, Japan

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2017年 / 82卷 / 13期

关键词：

CATALYZED S-ARYLATION; C-S; RADICAL ARYLATION; ROOM-TEMPERATURE; DIRECT CONVERSION; NICKEL-CATALYST; BOND FORMATION; SULFUR BONDS; THIOLS; PALLADIUM;

D O I：

10.1021/acs.joc.7b00767

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A novel synthesis of unsymmetrical aryl sulfides, which requires no transition metal catalyst and no oxidant, was developed. ThiS base-promoted cross-coupling reaction proceeded using arylhydrazines and 1 equiv amount of disulfides under inert gas conditions to afford the unsymmetrical aryl sulfides in good yields.

引用

页码：6647 / 6655

页数：9

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