A Simple Lithium(I) Salt with a Microporous Structure and Its Gas Sorption Properties

被引：90

作者：

Abrahams, Brendan F. ^{[1
]}

Grannas, Martin. J. ^{[1
]}

Hudson, Timothy A. ^{[1
]}

Robson, Richard ^{[1
]}

机构：

[1] Univ Melbourne, Sch Chem, Melbourne, Vic 3010, Australia

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 06期

基金：

澳大利亚研究理事会;

关键词：

coordination polymers; gas sorption; hydrogen; lithium; microporous materials; METAL-ORGANIC FRAMEWORK; ENHANCED HYDROGEN ADSORPTION; WALLED CARBON NANOTUBES; STORAGE;

D O I：

10.1002/anie.200906322

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Thoroughly absorbing: The simple combination of lithium ions and isonicotinate anions (1) leads to the formation of a lightweight salt (see picture; C black, O red, N blue, Li purple) that is able to reversibly sorb H2, N2, CO2, and CH4.The salt exists as a 3D network of microchannels that are occupied by solvent molecules. © 2010 Wiley-VCH Verlag GmbH & Co. KC.

引用

页码：1087 / 1089

页数：3

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