Esterification of high FFA tung oil with solid acid catalyst in fixed bed

被引：16

作者：

Li Lianhua ^{[1
]}

Lv Pengmei ^{[1
]}

Luo Wen ^{[1
]}

Wang Zhongming ^{[1
]}

Yuan Zhenhong ^{[1
]}

机构：

[1] Chinese Acad Sci, Key Lab Renewable Energy & Gas Hydrate, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China

来源：

BIOMASS & BIOENERGY | 2010年 / 34卷 / 04期

关键词：

Fixed bed reactor; Solid acid; Esterification; Tung oil; BIODIESEL PRODUCTION;

D O I：

10.1016/j.biombioe.2009.12.014

中图分类号：

S2 [农业工程];

学科分类号：

0828 ;

摘要：

The effect of molar ratio of methanol to oil, temperature and space velocity (SV) on pre-esterification of Tung oil was carried out in pilot-scale fixed bed reactor, with solid acid catalysts. The molar ratio results showed the maximum acid value reduction efficiency (90.21%) was obtained at the molar ratio of 8:1, the acid value decreased sharply to 0.70 g kg(-1) of KOH. And esterification reaction attained balance when space velocity was enough, so 0.029 h(-1) was optimal space velocity. Furthermore, activity of reactant and rate of reaction increase with temperature increased, and the maximum conversion was achieved at 65 C, the acid value of Tung oil could be reduced to 1.4 g kg(-1) of KOH. (C) 2009 Elsevier Ltd. All rights reserved.

引用

页码：496 / 499

页数：4

共 15 条

[1] Production of biodiesel from waste frying oil [J].