Oxidation of Thiols Using K2S2O8 in Ionic Liquid

被引：14

作者：

Hajipour, Abdol R. ^{[1
,2
]}

Mostafavi, Majid ^{[2
]}

Ruoho, Arnold E. ^{[1
]}

机构：

[1] Univ Wisconsin, Sch Med, Dept Pharmacol, Madison, WI 53706 USA

[2] Isfahan Univ Technol, Coll Chem, Pharmaceut Res Lab, Esfahan, Iran

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2009年 / 184卷 / 07期

基金：

美国国家卫生研究院;

关键词：

Disulfides; ionic liquid; K2S2O8; oxidation; thiols; NITROGEN DOUBLE-BONDS; BENZYLTRIPHENYLPHOSPHONIUM DICHROMATE; EFFICIENT OXIDANT; MILD REAGENT; CLEAVAGE; DEPROTECTION;

D O I：

10.1080/10426500802417000

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A green, straightforward, and novel method for oxidation of thiols to the corresponding disulfides is reported using K2S2O8 in the ionic liquid 1-butyl-3-methylimidazolium bromide [(bmim)Br] at 65-70 degrees C. The corresponding disulfides were obtained in excellent yield and short reaction time.

引用

页码：1920 / 1923

页数：4

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