The intrinsic temperature effect of Raman spectra of double-walled carbon nanotubes

被引:23
作者
Zhou, ZP
Ci, L
Song, L
Yan, XQ
Liu, DF
Yuan, HJ
Gao, Y
Wang, JX
Liu, LF
Zhou, WY
Xie, SS
Du, YX
Mo, YJ
机构
[1] Chinese Acad Sci, Ctr Condensed Matter Phys, Inst Phys, Grp A05, Beijing 100080, Peoples R China
[2] Henan Univ, Dept Phys, Kaifeng 475001, Peoples R China
基金
中国国家自然科学基金;
关键词
D O I
10.1016/j.cplett.2004.08.004
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The temperature-dependent Raman shift of double-walled carbon nanotubes (DWNTs) has been investigated in detail. It was found that radial breathing mode (RBM) frequencies of DWNTs have a linear dependence on the sample temperature, but different RBM frequencies correspond to completely different temperature coefficients. The frequency-dependent temperature coefficient has been investigated and attributed to the intershell effect in DWNTs. In comparison, G-band of DWNTs has a nonlinear or second-order polynomial relation with the increased temperature. The deviation from the linear trend has been revealed to be due to the contribution of the third- and fourth-order anharmonic term in the lattice potential energy with pure temperature effect. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:372 / 376
页数:5
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