Electrochemical fluorination of β-dicarbonyl compounds using p-iodotoluene difluoride as a mediator

被引：51

作者：

Hara, S ^{[1
]}

Hatakeyama, T ^{[1
]}

Chen, SQ ^{[1
]}

Ishi-i, K ^{[1
]}

Yoshida, M ^{[1
]}

Sawaguchi, M ^{[1
]}

Fukuhara, T ^{[1
]}

Yoneda, N ^{[1
]}

机构：

[1] Hokkaido Univ, Grad Sch Engn, Div Mol Chem, Sapporo, Hokkaido 060, Japan

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1998年 / 87卷 / 02期

关键词：

p-iodotoluene difluoride; alpha-fluoro-beta-dicarbonyl compounds; electrochemical fluorination;

D O I：

10.1016/S0022-1139(97)00144-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The selective and direct introduction of the fluorine atom into the alpha-position of beta-dicarbonyl compounds was electrochemically achieved using iodotoluene difluoride as the mediator. The resulting alpha-fluoro-beta-dicarbonyl compounds are important building blocks for biologically active compounds. (C) 1998 Elsevier Science S.A.

引用

页码：189 / 192

页数：4

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