Mesostructured silica tubes and rods by templating porous membranes

被引:61
作者
Liang, ZJ [1 ]
Susha, AS [1 ]
机构
[1] Max Planck Inst Colloids & Interfaces, D-14424 Potsdam, Germany
关键词
membranes; mesoporous materials; nanostructures; silicates; template synthesis;
D O I
10.1002/chem.200400005
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Mesostructured silica tubes and rods were prepared by deposition of a prehydrolysed silica sol with surfactant onto the cylindrical pores of a polycarbonate (PC) membrane template, followed by calcination to remove the surfactant and membrane template. The tubular and rodlike morphologies of mesostructured silica were demonstrated by scanning electron microscopy (SEM) and transmission electron microscopy (TEM) measurements. The tubes and rods show ordered hexagonal mesostructures, which were demonstrated by small angle X-ray diffraction (XRD) patterns and TEM measurements.
引用
收藏
页码:4910 / 4914
页数:5
相关论文
共 64 条
[1]   General predictive syntheses of cubic, hexagonal, and lamellar silica and titania mesostructured thin films [J].
Alberius, PCA ;
Frindell, KL ;
Hayward, RC ;
Kramer, EJ ;
Stucky, GD ;
Chmelka, BF .
CHEMISTRY OF MATERIALS, 2002, 14 (08) :3284-3294
[2]   Mesoporous silica synthesized by solvent evaporation: Spun fibers and spray-dried hollow spheres [J].
Bruinsma, PJ ;
Kim, AY ;
Liu, J ;
Baskaran, S .
CHEMISTRY OF MATERIALS, 1997, 9 (11) :2507-2512
[3]  
Cao HQ, 2001, ADV MATER, V13, P1393, DOI 10.1002/1521-4095(200109)13:18<1393::AID-ADMA1393>3.0.CO
[4]  
2-C
[5]   Preparation of polymeric micro- and nanostructures using a template-based deposition method [J].
Cepak, VM ;
Martin, CR .
CHEMISTRY OF MATERIALS, 1999, 11 (05) :1363-1367
[6]   Metal-nanocluster-filled carbon nanotubes: Catalytic properties and possible applications in electrochemical energy storage and production [J].
Che, GL ;
Lakshmi, BB ;
Martin, CR ;
Fisher, ER .
LANGMUIR, 1999, 15 (03) :750-758
[7]   Carbon nanotubule membranes for electrochemical energy storage and production [J].
Che, GL ;
Lakshmi, BB ;
Fisher, ER ;
Martin, CR .
NATURE, 1998, 393 (6683) :346-349
[8]   Bacterial templating of ordered macrostructures in silica and silica-surfactant mesophases [J].
Davis, SA ;
Burkett, SL ;
Mendelson, NH ;
Mann, S .
NATURE, 1997, 385 (6615) :420-423
[9]   Rapid and high-capacity immobilization of enzymes based on mesoporous silicas with controlled morphologies [J].
Fan, J ;
Lei, J ;
Wang, LM ;
Yu, CZ ;
Tu, B ;
Zhao, DY .
CHEMICAL COMMUNICATIONS, 2003, (17) :2140-2141
[10]   Interfacial synthesis of hollow microspheres of mesostructured silica [J].
Fowler, CE ;
Khushalani, D ;
Mann, S .
CHEMICAL COMMUNICATIONS, 2001, (19) :2028-2029