Correlation between PSD and adsorption of anionic dyes with different molecular weigths on activated carbon

被引：33

作者：

Aguiar, J. E. ^{[1
]}

de Oliveira, J. C. A. ^{[1
]}

Silvino, P. F. G. ^{[1
]}

Neto, J. A. ^{[1
]}

Silva, I. J., Jr. ^{[1
]}

Lucena, S. M. P. ^{[1
]}

机构：

[1] Univ Fed Ceara, Ctr Tecnol, Dept Engn Quim, GPSA, Campus Pici,Bloco 709, BR-60455760 Fortaleza, CE, Brazil

来源：

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS | 2016年 / 496卷

关键词：

Dyes; Adsorption; Activated Carbon; Molecular Simulation; PSD; PORE-SIZE DISTRIBUTIONS; COMPETITIVE ADSORPTION; WALL HETEROGENEITY; REACTIVE DYE; CONGO RED; ISOTHERMS; MODEL; NANOPARTICLES; ATRAZINE; BLUE;

D O I：

10.1016/j.colsurfa.2015.09.054

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The correlation between the adsorption capacity of commercial activated carbons and the pore size distributions in the removal of anionic dyes was investigated. We performed experimental adsorption isotherms measurements of the anionic dyes reactive red 120 (RR120), procion red MX-5B (PRMX-5B) and acid blue 25 (AB-25) in the activated carbons WV1050, Norit R1 and Maxsorb. The activated carbons were carefully characterized by N2 adsorption at 77 K and molecular simulation methods to obtain the PSDs and retention capacity of selected pores (8.9, 18.5 and 30.9 angstrom). Batch experiments were carried out in order to obtain single component dye isotherms. We found that the proposed selected pores of the PSD directly correlates with adsorption capacity when the size of the dye molecule is compatible with the carbon pore size. Between RR120 and PRMX-5B we noted that dye chemistry strongly affect the retention capacity. Based on our results, the use of N2 derived PSD and molecular simulation of dye retention in selected pores can be a useful tool to guide to the optimization of carbon-based adsorbents for dye removal. (C) 2015 Elsevier B.V. All rights reserved.

引用

页码：125 / 131

页数：7

共 36 条

[1] On the influence of heterogeneity of graphene sheets in the determination of the pore size distribution of activated carbons
Alexandre de Oliveira, J. C.
Lopez, R. H.
Toso, J. P.
Lucena, Sebastiao M. P.
Cavalcante, C. L., Jr.
Azevedo, D. C. S.
Zgrablich, G.
[J]. ADSORPTION-JOURNAL OF THE INTERNATIONAL ADSORPTION SOCIETY, 2011, 17 (05): : 845 - 851
[2] Allen M. P., 1987, COMPUTER SIMULATION
[3] [Anonymous], 1992, CONSTITUTION SLOVAK
[4] Density functional theory analysis of the influence of pore wall heterogeneity on adsorption in carbons
Bhatia, SK
[J]. LANGMUIR, 2002, 18 (18) : 6845 - 6856
[5] The effect of the choice of pore model on the characterization of the internal structure of microporous carbons using pore size distributions
Davies, GM
Seaton, NA
[J]. CARBON, 1998, 36 (10) : 1473 - 1490
[6] Calculation of pore size distributions of activated carbons from adsorption isotherms
Davies, GM
Seaton, NA
Vassiliadis, VS
[J]. LANGMUIR, 1999, 15 (23) : 8235 - 8245
[7] Analysis of mass transfer kinetics in the biosorption of synthetic dyes onto Spirulina platensis nanoparticles
Dotto, G. L.
Pinto, L. A. A.
[J]. BIOCHEMICAL ENGINEERING JOURNAL, 2012, 68 : 85 - 90
[8] Gregg S.J., 1982, ADSORPTION SURFACE A, V2nd, P303, DOI [10.1002/bbpc.19820861019, DOI 10.1002/BBPC.19820861019]
[9] UV/Visible spectroscopic studies of the effects of common salt and urea upon reactive dye solutions
Hamlin, JD
Phillips, DAS
Whiting, A
[J]. DYES AND PIGMENTS, 1999, 41 (1-2) : 137 - 142
[10] Decolorization of CI Basic Yellow 28 solution using supported ZnO nanoparticles coupled with photoelectro-Fenton process
Iranifam, M.
Zarei, M.
Khataee, A. R.
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2011, 659 (01) : 107 - 112

← 1 2 3 4 →