Preparation of rGO@Fe3O4 nanocomposite and its application to enhance the thermal conductivity of epoxy resin

被引:31
作者
Geng, Jiaqi [1 ]
Men, Yuanli [1 ]
Liu, Chen [1 ]
Ge, Xiang [2 ]
Yuan, Caideng [1 ]
机构
[1] Tianjin Univ, Sch Chem Engn & Technol, Dept Polymer Sci & Engn, Tianjin 300350, Peoples R China
[2] Tianjin Univ, Sch Mech Engn, Minist Educ, Key Lab Mech Theory & Equipment Design, Tianjin 300354, Peoples R China
关键词
MECHANICAL-PROPERTIES; POLYMER COMPOSITES; GRAPHENE; NANOPARTICLES; DEPENDENCE; NANOSHEETS;
D O I
10.1039/d1ra02254g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In this study, we report a simple method to improve the thermal conductivity of epoxy resin by using new magnetic composites as fillers. The rGO@Fe3O4 nanocomposite has been prepared by a solvothermal method, and its morphology and chemical structure were characterized and analyzed by various characterization methods. Afterwards, the rGO@Fe3O4/EP composite material was obtained in an external magnetic field, in which the rGO@Fe3O4 is uniformly dispersed in the epoxy resin matrix, arranged along the direction of the magnetic field. In addition, the orientation of rGO@Fe3O4 increases with the magnetic field intensity. After doping 30% (wt) rGO@Fe3O4 into epoxy resin and curing under a 500 Gs magnetic field, the rGO@Fe3O4/EP composite material is anisotropic and has a higher thermal conductivity (increased by 196.60%) parallel to the direction of the magnetic field compared to a pure ring oxygen resin.
引用
收藏
页码:16592 / 16599
页数:8
相关论文
共 43 条
[31]   X-RAY PHOTOELECTRON-SPECTROSCOPY STUDIES OF SOLVATED METAL ATOM DISPERSED CATALYSTS - MONOMETALLIC IRON AND BIMETALLIC IRON COBALT PARTICLES ON ALUMINA [J].
TAN, BJ ;
KLABUNDE, KJ ;
SHERWOOD, PMA .
CHEMISTRY OF MATERIALS, 1990, 2 (02) :186-191
[32]   Preparation and properties of cyanate-based wave-transparent laminated composites reinforced by dopamine/POSS functionalized Kevlar cloth [J].
Tang, Lin ;
Dang, Jing ;
He, Mukun ;
Li, Junyou ;
Kong, Jie ;
Tang, Yusheng ;
Gu, Junwei .
COMPOSITES SCIENCE AND TECHNOLOGY, 2019, 169 :120-126
[33]   The effect of graphene dispersion on the mechanical properties of graphene/epoxy composites [J].
Tang, Long-Cheng ;
Wan, Yan-Jun ;
Yan, Dong ;
Pei, Yong-Bing ;
Zhao, Li ;
Li, Yi-Bao ;
Wu, Lian-Bin ;
Jiang, Jian-Xiong ;
Lai, Guo-Qiao .
CARBON, 2013, 60 :16-27
[34]   Fabrication and investigations on the polydopamine/KH-560 functionalized PBO fibers/cyanate ester wave-transparent composites [J].
Tang, Yusheng ;
Dong, Wencai ;
Tang, Lin ;
Zhang, YiKun ;
Kong, Jie ;
Gu, Junwei .
COMPOSITES COMMUNICATIONS, 2018, 8 :36-41
[35]   Mechanical-Thermal-Electrical and Morphological Properties of Graphene Reinforced Polymer Composites: A Review [J].
Verma, Deepak ;
Gope, P. C. ;
Shandilya, Abhinav ;
Gupta, Ayush .
TRANSACTIONS OF THE INDIAN INSTITUTE OF METALS, 2014, 67 (06) :803-816
[36]   Grafting of epoxy chains onto graphene oxide for epoxy composites with improved mechanical and thermal properties [J].
Wan, Yan-Jun ;
Tang, Long-Cheng ;
Gong, Li-Xiu ;
Yan, Dong ;
Li, Yi-Bao ;
Wu, Lian-Bin ;
Jiang, Jian-Xiong ;
Lai, Guo-Qiao .
CARBON, 2014, 69 :467-480
[37]  
Xie C.S, 2007, MAT REP, V21, P171
[38]  
[谢宇宁 Xie Yuning], 2018, [工程塑料应用, Engineering Plastics Application], V46, P143
[39]   Enhanced thermal conductivity in polymer composites with aligned graphene nanosheets [J].
Yan, Haiyan ;
Tang, Yanxia ;
Long, Wei ;
Li, Yongfei .
JOURNAL OF MATERIALS SCIENCE, 2014, 49 (15) :5256-5264
[40]   Nanoscaled self-alignment of Fe3O4 nanodiscs in ultrathin rGO films with engineered conductivity for electromagnetic interference shielding [J].
Yang, Yong ;
Li, Meng ;
Wu, Yuping ;
Wang, Tao ;
Choo, Eugene Shi Guang ;
Ding, Jun ;
Zong, Baoyu ;
Yang, Zhihong ;
Xue, Junmin .
NANOSCALE, 2016, 8 (35) :15989-15998