Gel-Spun Polyacrylonitrile Fiber From Pregelled Spinning Solution

被引:25
作者
Tan, Lianjiang [1 ]
Liu, Shuiping [1 ]
Song, Kunyang [1 ]
Chen, Huifang [1 ]
Pan, Ding [1 ]
机构
[1] Donghua Univ, State Key Lab Modificat Chem Fibers & Polymer Mat, Shanghai 201620, Peoples R China
关键词
BEHAVIOR; GELATION;
D O I
10.1002/pen.21654
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Polyacrylonitrile (PAN) fibers have been gel spun from pregelled PAN spinning solution. The pregelled solution had network structure with elevated spinnability, the as-spun fiber from which had more circular cross-section and reduced skin-core difference. Drawing was more effective in inducing the segmental orientation and crystallization in gel-spun fiber than in dry-wet spun fiber. The mechanical properties of the gel-spun fiber were better than those of the dry-wet spun fiber after multi-stage drawing. POLYM. ENG. SCI., 50:12901294, 2010. (C) 2010 Society of Plastics Engineers
引用
收藏
页码:1290 / 1294
页数:5
相关论文
共 14 条
[1]   MICROTEXTURE AND STRUCTURE OF SOME HIGH-TENSILE STRENGTH, PAN-BASE CARBON-FIBERS [J].
GUIGON, M ;
OBERLIN, A ;
DESARMOT, G .
FIBRE SCIENCE & TECHNOLOGY, 1984, 20 (01) :55-72
[2]  
GUPTA AK, 1991, J MACROMOL SCI REV C, V31, P13
[3]   Effect of jet stretch on polyacrylonitrile as-spun fiber formation [J].
Ji, Bao-Hua ;
Wang, Cheng-Guo ;
Wang, Yan-Xiang .
JOURNAL OF APPLIED POLYMER SCIENCE, 2007, 103 (05) :3348-3352
[4]   Rheological characterisation of polymer gels [J].
Kavanagh, GM ;
Ross-Murphy, SB .
PROGRESS IN POLYMER SCIENCE, 1998, 23 (03) :533-562
[5]  
Kobashi T, 1987, USA, Patent No. 4659529
[6]  
KRIGBAUM WR, 1960, J POLYM SCI, V43, P647
[7]   Thermal-induced simultaneous liquid-liquid phase separation and liquid-solid transition in aqueous polyurethane dispersions [J].
Madbouly, SA ;
Otaigbe, JU ;
Nanda, AK ;
Wicks, DA .
POLYMER, 2005, 46 (24) :10897-10907
[8]  
Qian BJ, 1996, J POLYM ENG, V15, P327
[9]  
Sen K, 1996, J MACROMOL SCI R M C, VC36, P1
[10]   A SEMIEMPIRIC MODEL FOR ESTABLISHING THE DRAWABILITY OF SOLUTION-SPUN LINEAR POLYAMIDES AND OTHER FLEXIBLE CHAIN POLYMERS [J].
SMOOK, J ;
VOS, GJH ;
DOPPERT, HL .
JOURNAL OF APPLIED POLYMER SCIENCE, 1990, 41 (1-2) :105-116