Rings and chains in solid-state metal borides and borocarbides. The electron count matters

被引:11
作者
Lassoued, Souheila [1 ,3 ]
Gautier, Regis [1 ]
Boutarfaia, Ahmed [2 ]
Halet, Jean-Francois [1 ]
机构
[1] Univ Rennes 1, Ecole Natl Super Chim Rennes, CNRS, UMR 6226, F-35042 Rennes, France
[2] Univ Merbah Kasdi Ouargla, Fac Sci & Technol & Sci Matiere, Ouargla, Algeria
[3] Univ Mohamed Khider, Lab Chim Appl, Biskra 07000, Algeria
关键词
Borides; Borocarbides; Solid-state compounds; Electron counting; Theoretical calculations; STRUCTURAL-ANALYSIS; CRYSTAL-STRUCTURE; PHYSICAL-PROPERTIES; COLORING PROBLEM; ONE-DIMENSION; MB2C2; M; CARBON; COMPLEXES; AZULENE; RE;
D O I
10.1016/j.jorganchem.2009.11.037
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The bonding and structural arrangement in a few representative ring-or chain-containing solid-state metal borides and borocarbides are analyzed with respect to the electron count of the non-metal entities. Similarities (and differences) with molecular analogs are emphasized. (C) 2009 Elsevier B. V. All rights reserved.
引用
收藏
页码:987 / 993
页数:7
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