Ultrafine niobate ceramic powders in the system RExLi1-xNbO3 (RE: La, Pr, Sm, Er) synthesized by polymerizable complex method

被引：15

作者：

Popa, M ^{[1
]}

Kakihana, M ^{[1
]}

机构：

[1] Tokyo Inst Technol, Mat & Struct Lab, Midori Ku, Yokohama, Kanagawa 2268503, Japan

来源：

CATALYSIS TODAY | 2003年 / 78卷 / 1-4期

关键词：

LiNbO3; rare earth substitution; polymerizable complex technique; nanopowders; Raman spectroscopy; fluorescence;

D O I：

10.1016/S0920-5861(02)00345-0

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Nanopowders of lithium niobate LiNbO3 and rare earth (RE) substituted LiNbO3-RExLi1-xNbO3, x = 0.05 (RE: La, Pr, Sm, Er) were synthesized using a simple technique as the polymerizable complex method, based on the Pechini-type reaction route. A mixed solution of citric acid and ethylene glycol with Li, Nb and RE ions was polymerized. The formation mechanism, the homogeneity and the structure of the obtained powders have been investigated by thermogravimetry, X-ray diffraction, Raman spectroscopy and scanning electron microscopy measurements. The X-ray diffraction analysis indicated the formation of perovskite-type oxides, which crystallize in rhombohedral system when the Li-Nb and Li-Nb-RE polymeric precursors were treated at temperatures as low as 500degreesC for 2 h. No additional crystalline phases formed during calcinations, but shifting of the XRD peaks with the RE ion substitution for Li suggested that structural modification inside the LN is the same. The Raman spectroscopy data of LiNbO3 substituted by RE were compared to the results of the unsubstituted system. The substitution dependence of frequency and damping in the A(1)(TO2), A(1)(TO3) and E(TO2) modes were employed to deduce the incorporation site of RE ions in LiNbO3 (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：519 / 527

页数：9

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