Bench-Stable Nickel Precatalysts with Heck-type Activation

被引：28

作者：

Weber, Jessica M. ^{[1
]}

Longstreet, Ashley R. ^{[1
,2
]}

Jamison, Timothy F. ^{[1
]}

机构：

[1] MIT, Dept Chem, Cambridge, MA 02139 USA

[2] Univ Tampa, Dept Chem Biochem & Phys, 401 West Kennedy Blvd, Tampa, FL 33606 USA

来源：

ORGANOMETALLICS | 2018年 / 37卷 / 16期

基金：

美国国家科学基金会;

关键词：

ALPHA-OLEFINS; CATALYSIS; ALDEHYDES; ALKENES; EFFICIENT;

D O I：

10.1021/acs.organomet.8b00351

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Herein, we report the synthesis and characterization of a new class of air-and moisture-stable phosphine-containing nickel(II) precatalysts, which activate through a Heck-type mechanism. The activities of the precatalysts are demonstrated with a carbonyl ene coupling reaction.

引用

页码：2716 / 2722

页数：7