Bench-Stable Nickel Precatalysts with Heck-type Activation

被引：28
|
作者：
Weber, Jessica M. [1 ]
Longstreet, Ashley R. [1 ,2 ]
Jamison, Timothy F. [1 ]
机构：
[1] MIT, Dept Chem, Cambridge, MA 02139 USA
[2] Univ Tampa, Dept Chem Biochem & Phys, 401 West Kennedy Blvd, Tampa, FL 33606 USA
来源：
ORGANOMETALLICS | 2018年 / 37卷 / 16期
基金：
美国国家科学基金会;
关键词：
ALPHA-OLEFINS; CATALYSIS; ALDEHYDES; ALKENES; EFFICIENT;
D O I：
10.1021/acs.organomet.8b00351
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Herein, we report the synthesis and characterization of a new class of air-and moisture-stable phosphine-containing nickel(II) precatalysts, which activate through a Heck-type mechanism. The activities of the precatalysts are demonstrated with a carbonyl ene coupling reaction.
引用
收藏
页码：2716 / 2722
页数：7
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