Measurement and Modeling of Biodiesel Cold-Flow Properties

被引：36

作者：

Coutinho, Joao A. P. ^{[1
]}

Goncalves, M. ^{[1
]}

Pratas, M. J.

Batista, M. L. S. ^{[1
]}

Fernandes, V. F. S. ^{[1
]}

Pauly, J. ^{[2
]}

Daridon, J. L. ^{[2
]}

机构：

[1] Univ Aveiro, Ctr Invest Mat Ceram & Compositos CICECO, Dept Quim, P-3810193 Aveiro, Portugal

[2] Univ Pau, Lab Fluides Complexes, Ctr Univ Rech Sci, F-64013 Pau, France

来源：

ENERGY & FUELS | 2010年 / 24卷 / 04期

关键词：

LOW-TEMPERATURE PROPERTIES; LOCAL COMPOSITION MODELS; SOLID-LIQUID EQUILIBRIA; WAX FORMATION; DIESEL FUELS; METHYL-ESTERS; HIGH-PRESSURE; PREDICTIVE UNIQUAC; CRYSTALLIZATION; SYSTEMS;

D O I：

10.1021/ef901427g

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

Despite their interest for the understanding of the low-temperature behavior of biodiesel, data on the phase equilibria of biodiesels at temperatures below the cloud point are not available in the literature. To overcome this limitation, the liquid- and solid-phase compositions and fractions at temperatures below the cloud point were studied for three commercial diesels at temperatures ranging from 260 to 275 K. A thermodynamic framework able to describe these multiphase systems is presented. Two versions of the predictive UNIQUAC model along with an approach assuming complete immiscibility of the compounds in the solid phase are evaluated with success against the experimental phase equilibrium data measured in this work.

引用

页码：2667 / 2674

页数：8