Formation of radical ions and peculiarities of optical limiting in solution, containing C60, perylene, and tetramethylbenzidine

被引:0
作者
Gryaznova, M. V. [1 ]
Danilov, V. V. [1 ]
Ermolaeva, G. M. [1 ]
Khrebtov, A. I. [1 ]
Shakhverdov, T. A. [1 ]
机构
[1] Res Corp SI Vavilov State Opt Inst, Inst Laser Phys, 12 Birzhevaya Line, St Petersburg 199034, Russia
来源
LASER OPTICS 2006: WAVEFRONT TRANSFORMATION AND LASER BEAM CONTROL | 2007年 / 6613卷
关键词
electron transfer; radical ions; optical limiting; all-optical switching; fullerene C-60;
D O I
10.1117/12.739368
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
Spectral and some nonlinear optical properties of multicomponent solutions, which contain fullerene C-60, perylene, and tetramethylbenzidine, are investigated. In such systems, enhanced optical limiting and all-optical switching are due to a formation of radical ions by a photoinduced electron transfer. A diagram of electronic states is thermodynamically calculated and prove for efficiency of the photoinduced electron transfer via the excited singlet state of C-60 is shown.
引用
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页数:6
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