Regio- and Stereocontrol in Rhenium-Catalyzed Transposition of Allylic Alcohols

被引：77

作者：

Herrmann, Aaron T. ^{[1
]}

Saito, Tatsuo ^{[1
]}

Stivala, Craig E. ^{[1
]}

Tom, Janine ^{[1
]}

Zakarian, Armen ^{[1
]}

机构：

[1] Univ Calif Santa Barbara, Dept Chem & Biochem, Santa Barbara, CA 93106 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2010年 / 132卷 / 17期

基金：

日本学术振兴会;

关键词：

METAL OXO COMPLEXES; MOLYBDENUM COMPLEXES; SILYL ETHERS; ISOMERIZATION; 1,3-ISOMERIZATION;

D O I：

10.1021/ja101673v

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A hydroxyl group-directed, highly regio- and stereoselective transposition of allylic alcohols based on rhenium catalysis has been developed. The method is suitable for a direct isomerization of acetals into the thermodynamically preferred isomer as long as one of the hydroxyl groups is allylic. This method will expand the scope of rhenium-catalyzed alcohol transpositions for complex molecule synthesis.

引用

页码：5962 / +

页数：3

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