Selective encapsulation of a chloride anion in a 1H-pyrazole Cu2+ metallocage

被引：5

作者：

Pitarch-Jarque, Javier ^{[1
]}

Jimenez, Hermas R. ^{[1
]}

Kalenius, Elina ^{[2
]}

Blasco, Salvador ^{[1
]}

Lopera, Alberto ^{[1
]}

Clares, M. Paz ^{[1
]}

Rissanen, Kari ^{[2
]}

Garcia-Espana, Enrique ^{[1
]}

机构：

[1] Univ Valencia, Inst Ciencia Mol, Catedrat Jose Beltran Martinez 2, Paterna 46980, Spain

[2] Univ Jyvaskyla, Dept Chem, POB 35, FI-40014 Jyvaskyla, Finland

来源：

DALTON TRANSACTIONS | 2021年 / 50卷 / 26期

关键词：

RECEPTOR; COMPLEX; VISUALIZATION; EQUILIBRIUM; HALIDES; WATER; PH;

D O I：

10.1039/d1dt01302e

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A self-assembled metallobox from copper(ii) and two macrocycles containing 1H-pyrazole ligands has been prepared. The internal cavity of the box is able to selectively encapsulate a single chloride anion over any other halide anion.

引用

页码：9010 / 9015

页数：6

共 37 条

[1] An Automatic Molecular Dispenser of Chloride [J].

Alibrandi, Giuseppe ;

Amendola, Valeria ;

Bergamaschi, Greta ;

Dollenz, Riccardo ;

Fabbrizzi, Luigi ;

Licchelli, Maurizio ;

Lo Vecchio, Carmelo .

CHEMISTRY-A EUROPEAN JOURNAL, 2013, 19 (11) :3729-3734

[2] A new macrocyclic cryptand with squaramide moieties:: An overstructured CuII complex that selectively binds halides:: Synthesis, acid/base- and ligational behavior, and crystal structures [J].

Ambrosi, Gianluca ;

Formica, Mauro ;

Fusi, Vieri ;

Giorgi, Luca ;

Guerri, Annalisa ;

Micheloni, Mauro ;

Paoli, Paola ;

Pontellini, Roberto ;

Rossi, Patrizia .

CHEMISTRY-A EUROPEAN JOURNAL, 2007, 13 (02) :702-712

[3]

Amendola V, 2000, ANGEW CHEM INT EDIT, V39, P2917, DOI 10.1002/1521-3773(20000818)39:16<2917::AID-ANIE2917>3.3.CO

[4]

2-S

[5]

[Anonymous], 2012, CRYSALISPRO 1 171 36

[6]

[Anonymous], 2017, CRYSTALEXPLORER17

[7] Hexabromide salt of a tiny octaazacryptand as a receptor for encapsulation of lower homolog halides: structural evidence on halide selectivity inside the tiny cage [J].

Arunachalam, M. ;

Suresh, Eringathodi ;

Ghosh, Pradyut .

TETRAHEDRON, 2007, 63 (46) :11371-11376

[8] Anion encapsulation and dynamics in self-assembled coordination cages [J].

Custelcean, Radu .

CHEMICAL SOCIETY REVIEWS, 2014, 43 (06) :1813-1824

[9] A metallacage encapsulating chloride as a probe for a solvation scale in ionic liquids [J].

Daguenet, Corinne ;

Dyson, Paul J. .

INORGANIC CHEMISTRY, 2007, 46 (02) :403-408

[10] Anion-templated synthesis of metallacages as a means for the colorimetric detection of chlorides [J].

Diaz, P ;

Mingos, DMP ;

Vilar, R ;

White, AJP ;

Williams, DJ .

INORGANIC CHEMISTRY, 2004, 43 (24) :7597-7604

← 1 2 3 4 →