Three-dimensional inhomogeneities in PEDOT:PSS films

被引：173

作者：

Kemerink, M

Timpanaro, S

de Kok, MM

Meulenkamp, EA

Touwslager, FJ

机构：

[1] Eindhoven Univ Technol, Dept Appl Phys, NL-5600 MB Eindhoven, Netherlands

[2] Philips Res Labs, NL-5656 AA Eindhoven, Netherlands

来源：

JOURNAL OF PHYSICAL CHEMISTRY B | 2004年 / 108卷 / 49期

关键词：

D O I：

10.1021/jp0464674

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Spin-cast PEDOT/PSS film are investigated using scanning probe-based spectroscopic techniques. The films are found to consist of relatively well-conducting islands that are embedded in a less conductive matrix. A scanning-tunneling microscope-based method is developed to obtain three-dimensional conductivity images with nanometer resolution. Order-of-magnitude variations in the film conductivity are observed in all spatial directions. In addition, charge transport in the normal direction depends on the injection spot and is found to be ohmic or space-charge-limited. We found that both the morphology and the conductivity of the top layer differ substantially from those in the bulk, which is attributed to an enhanced PSS content in the top layer.

引用

页码：18820 / 18825

页数：6

共 50 条

[31] The Determination of Mega Permittivity in PEDOT-PSS Films [J].

Bindu, S. ;

Panda, Subodh Kumar ;

Rekha, P. .

BIOSCIENCE BIOTECHNOLOGY RESEARCH COMMUNICATIONS, 2020, 13 (13) :9-14

[32] Decohesion Kinetics of PEDOT: PSS Conducting Polymer Films [J].

Dupont, Stephanie R. ;

Novoa, Fernando ;

Voroshazi, Eszter ;

Dauskardt, Reinhold H. .

ADVANCED FUNCTIONAL MATERIALS, 2014, 24 (09) :1325-1332

[33] Variation of Interfacial Capacitance in PEDOT-PSS Films [J].

Bindu, S. ;

Panda, Subodh Kumar ;

Rekha, P. .

BIOSCIENCE BIOTECHNOLOGY RESEARCH COMMUNICATIONS, 2020, 13 (13) :28-33

[34] PEDOT: PSS-Modified Organic Flexible and Implantable Microelectrode for Internal Bi-Directional Electrophysiology of Three-Dimensional Cardiomyocyte Spheroid [J].

Yuan, Qunchen ;

Qin, Chunlian ;

Xu, Dongxin ;

Qiu, Yong ;

Hu, Jiahao ;

Wan, Hao ;

Hu, Ning ;

Wang, Ping .

ACS SENSORS, 2024, 10 (01) :460-469

[35] Picosecond laser patterning of PEDOT:PSS thin films [J].

Semaltianos, N. G. ;

Koidis, C. ;

Pitsalidis, C. ;

Karagiannidis, P. ;

Logothetidis, S. ;

Perrie, W. ;

Liu, D. ;

Edwardson, S. P. ;

Fearon, E. ;

Potter, R. J. ;

Dearden, G. ;

Watkins, K. G. .

SYNTHETIC METALS, 2011, 161 (5-6) :431-439

[36] PEDOT:PSS Schottky contacts on annealed ZnO films [J].

朱亚彬 ;

胡伟 ;

纳杰 ;

何帆 ;

周岳亮 ;

陈聪 .

Chinese Physics B, 2011, 20 (04) :446-449

[37] ZnO flower/PEDOT:PSS thermoelectric composite films [J].

Yong Du ;

Kefeng Cai ;

Shirley Z. Shen ;

Weidong Yang ;

Jiayue Xu ;

Tong Lin .

Journal of Materials Science: Materials in Electronics, 2016, 27 :10289-10293

[38] PEDOT:PSS Schottky contacts on annealed ZnO films [J].

Zhu Ya-Bin ;

Hu Wei ;

Na Jie ;

He Fan ;

Zhou Yue-Liang ;

Chen Cong .

CHINESE PHYSICS B, 2011, 20 (04)

[39] ZnO flower/PEDOT:PSS thermoelectric composite films [J].

Du, Yong ;

Cai, Kefeng ;

Shen, Shirley Z. ;

Yang, Weidong ;

Xu, Jiayue ;

Lin, Tong .

JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2016, 27 (10) :10289-10293

[40] Surface charging suppression using PEDOT/PSS in the fabrication of three dimensional structures on a quartz substrate [J].

Mohamed, K. ;

Alkaisi, M. M. ;

Blaikie, R. J. .

MICROELECTRONIC ENGINEERING, 2009, 86 (4-6) :535-538

← 1 2 3 4 5 →