Cross Coupling of Arylboronic Acids with Imidazoles by Sulfonatocopper(II)(salen) Complex in Water

被引：16
作者：
Wang, Lixia [1 ]
Jiang, Zhaoqiong [1 ]
Yu, Lintao [1 ]
Li, Lili [1 ]
Li, Zhengkai [1 ]
Zhou, Xiangge [1 ,2 ]
机构：
[1] Sichuan Univ, Inst Homogeneous Catalysis, Coll Chem, Chengdu 610064, Peoples R China
[2] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China
来源：
CHEMISTRY LETTERS | 2010年 / 39卷 / 07期
关键词：
ESTROGEN-RECEPTOR; ORGANIC-REACTIONS; ROOM-TEMPERATURE; N-ARYLATION; LIGANDS; ARYL; 1H-IMIDAZOLES; DERIVATIVES; INHIBITORS; CHLORIDES;
D O I：
10.1246/cl.2010.764
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A mild and clean protocol for the cross coupling reactions between imidazoles and arylboronic acids has been developed in good to excellent yields up to 98% in the presence of sulfonatocopper(II)(salen) catalyst in water without addition of other additives and bases.
引用
收藏
页码：764 / 765
页数：2
相关论文
共 26 条
  • [1] AKIYA N, 2005, CHEM REV, V105, P3095
  • [2] Low-pressure solubility of carbon dioxide in room-temperature ionic liquids measured with a quartz crystal microbalance
    Baltus, RE
    Culbertson, BH
    Dai, S
    Luo, HM
    DePaoli, DW
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (02) : 721 - 727
  • [3] Water in organocatalytic processes: Debunking the myths
    Blackmond, Donna G.
    Armstrong, Alan
    Coombe, Vyv
    Wells, Andrew
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (21) : 3798 - 3800
  • [4] Applications of and alternatives to π-electron-deficient azine organometallics in metal catalyzed cross-coupling reactions
    Campeau, Louis-Charles
    Fagnou, Keith
    [J]. CHEMICAL SOCIETY REVIEWS, 2007, 36 (07) : 1058 - 1068
  • [5] The [Cu(OH)•TMEDA]2Cl2-catalyzed coupling of arylboronic acids with imidazoles in water
    Collman, JP
    Zhong, M
    Zeng, L
    Costanzo, S
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 2001, 66 (04) : 1528 - 1531
  • [6] An efficient diamine copper complex-catalyzed coupling of arylboronic acids with imidazoles
    Collman, JP
    Zhong, M
    [J]. ORGANIC LETTERS, 2000, 2 (09) : 1233 - 1236
  • [7] Solid supported aryl/heteroaryl C-N cross-coupling reactions.
    Combs, AP
    Saubern, S
    Rafalski, M
    Lam, PYS
    [J]. TETRAHEDRON LETTERS, 1999, 40 (09) : 1623 - 1626
  • [8] IMIDAZOL-1-YL AND PYRIDIN-3-YL DERIVATIVES OF 4-PHENYL-1,4-DIHYDROPYRIDINES COMBINING CA2+ ANTAGONISM AND THROMBOXANE-A(2) SYNTHASE INHIBITION
    COZZI, P
    CARGANICO, G
    FUSAR, D
    GROSSONI, M
    MENICHINCHERI, M
    PINCIROLI, V
    TONANI, R
    VAGHI, F
    SALVATI, P
    [J]. JOURNAL OF MEDICINAL CHEMISTRY, 1993, 36 (20) : 2964 - 2972
  • [9] Organocatalysis by N-heterocyclic, carbenes
    Enders, Dieter
    Niemeier, Oliver
    Henseler, Alexander
    [J]. CHEMICAL REVIEWS, 2007, 107 (12) : 5606 - 5655
  • [10] Dialkylphosphinoimidazoles as new ligands for palladium-catalyzed coupling reactions of aryl chlorides
    Harkal, S
    Rataboul, F
    Zapf, A
    Fuhrmann, C
    Riermeier, T
    Monsees, A
    Beller, M
    [J]. ADVANCED SYNTHESIS & CATALYSIS, 2004, 346 (13-15) : 1742 - 1748
123