Cerium-based UiO-66 metal-organic frameworks explored as efficient redox catalysts: titanium incorporation and generation of abundant oxygen vacancies

被引:85
作者
Zhang, Yajun [1 ]
Chen, Hanjiao [1 ]
Pan, Yi [1 ,2 ]
Zeng, Xiaoliang [1 ]
Jiang, Xiaofang [1 ]
Long, Zhou [1 ]
Hou, Xiandeng [1 ,3 ]
机构
[1] Sichuan Univ, Analyt & Testing Ctr, Chengdu 610064, Sichuan, Peoples R China
[2] Natl Inst Measurement & Testing Technol, Inst Chem, Chengdu 610021, Sichuan, Peoples R China
[3] Sichuan Univ, Dept Chem, Chengdu 610064, Sichuan, Peoples R China
关键词
LIGHT; MOF; CO2; PERFORMANCE; WATER; PHOTOCATALYST; ADSORPTION; REDUCTION; BEHAVIOR; REMOVAL;
D O I
10.1039/c9cc06562h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The recently developed UiO-66(Ce) was firstly endowed with greatly improved redox photocatalytic activity based on titanium incorporation, which for the first time induced the formation of oxygen vacancies in Ce-MOFs, and then promoted the generation of oxidative (OH)-O-center dot/O-center dot(2)- and reductive electrons.
引用
收藏
页码:13959 / 13962
页数:4
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