Water Hydrogen Bond Structure near Highly Charged Interfaces Is Not Like Ice

被引：149

作者：

Nihonyanagi, Satoshi ^{[1
]}

Yamaguchi, Shoichi ^{[1
]}

Tahara, Tahei ^{[1
]}

机构：

[1] RIKEN, Mol Spect Lab, ASI, Wako, Saitama 3510198, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2010年 / 132卷 / 20期

关键词：

FREQUENCY VIBRATIONAL SPECTROSCOPY; RAMAN-SPECTRA; LIQUID WATER; GENERATION SPECTROSCOPY; AQUEOUS-SOLUTIONS; MOLECULES; SURFACE; RELAXATION; MONOLAYERS; STRENGTH;

D O I：

10.1021/ja910914g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Imaginary x((2)) spectra of HOD at air/charged surfactant/aqueous interfaces highly resemble the IR spectrum of the bulk liquid HOD, showing no indication of the "ice-like" structure. Clearly, the hydrogen bond structures at highly charged interfaces are not like ice but very similar to the structure in the bulk.

引用

页码：6867 / +

页数：4

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