Visible-Light-Induced Sulfur-Alkenylation of Alkenes

被引：16
|
作者：
Xu, Qi [1 ]
Zhou, Xiaoxuan [1 ]
Zhang, Si [1 ]
Pan, Ling [1 ]
Liu, Qun [1 ]
Li, Yifei [1 ]
机构：
[1] Northeast Normal Univ, Dept Chem, Jilin Prov Key Lab Organ Funct Mol Design & Synth, Changchun 130024, Peoples R China
来源：
ORGANIC LETTERS | 2021年 / 23卷 / 12期
基金：
中国国家自然科学基金;
关键词：
DICARBOFUNCTIONALIZATION; STYRENES;
D O I：
10.1021/acs.orglett.1c01596
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A visible-light-induced intermolecular sulfur-alkenylation of alkenes, including both activated and unactivated alkenes, is described. This sulfur-alkenylation reaction proceed in a highly regio- and stereospecific manner involving the visible-light-induced conversion of a ketene dithioacetal to the thiavinyl 1,3-dipole intermediate, followed by a formal [3 + 2] cycloaddition and C-S bond cleavage. Furthermore, it is also an efficient approach for the late-stage functionalization of natural products and complex molecules, even being induced by sunlight under ambient conditions.
引用
收藏
页码：4870 / 4875
页数：6
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