An in situ investigation of the water-induced phase transformation of UTSA-74 to MOF-74(Zn)

被引：25
作者：
Bueken, Bart [1 ]
Reinsch, Helge [2 ]
Heidenreich, Niclas [2 ]
Vandekerkhove, Annelies [1 ]
Vermoortele, Frederik [1 ]
Kirschhock, Christine E. A. [1 ]
Stock, Norbert [2 ]
De Vos, Dirk [1 ]
Ameloot, Rob [1 ]
机构：
[1] Katholieke Univ Leuven, Dept M2S, Ctr Surface Chem & Catalysis, Celestijnenlaan 200F POB 2461, B-3001 Leuven, Belgium
[2] Christian Albrechts Univ Kiel, Inst Anorgan Chem, Max Eyth Str 2, D-24118 Kiel, Germany
来源：
CRYSTENGCOMM | 2017年 / 19卷 / 29期
基金：
瑞典研究理事会; 比利时弗兰德研究基金会;
关键词：
METAL-ORGANIC FRAMEWORKS; X-RAY-DIFFRACTION; CARBON-DIOXIDE; HYDROGEN STORAGE; HIGH-THROUGHPUT; TIME; MECHANISM; CO; CRYSTALLIZATION; SEPARATIONS;
D O I：
10.1039/c7ce00094d
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
We report the water-induced transformation of the [Zn-2(dobdc)] (dobdc = 2,5-dioxidobenzene-1,4-dicarboxylate) metal-organic framework UTSA-74 to its polymorph MOF-74.Zn), contrary to a previous report on the stability of UTSA-74 under such conditions. This dissolution-recrystallization process was investigated using time-resolved in situ X-ray diffraction and kinetically analyzed using the Gualtieri crystallization model.
引用
收藏
页码：4152 / 4156
页数：5
相关论文
共 41 条
[1]   High-Throughput and Time-Resolved Energy-Dispersive X-Ray Diffraction (EDXRD) Study of the Formation of CAU-1-(OH)2: Microwave and Conventional Heating [J].
Ahnfeldt, Tim ;
Moellmer, Jens ;
Guillerm, Vincent ;
Staudt, Reiner ;
Serre, Christian ;
Stock, Norbert .
CHEMISTRY-A EUROPEAN JOURNAL, 2011, 17 (23) :6462-6468
[2]  
[Anonymous], 2005, ANGEW CHEM
[3]   High Propene/Propane Selectivity in Isostructural Metal-Organic Frameworks with High Densities of Open Metal Sites [J].
Bae, Youn-Sang ;
Lee, Chang Yeon ;
Kim, Ki Chul ;
Farha, Omar K. ;
Nickias, Peter ;
Hupp, Joseph T. ;
Nguyen, SonBinh T. ;
Snurr, Randall Q. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (08) :1857-1860
[4]   Reversible CO Binding Enables Tunable CO/H2 and CO/N2 Separations in Metal-Organic Frameworks with Exposed Divalent Metal Cations [J].
Bloch, Eric D. ;
Hudson, Matthew R. ;
Mason, Jarad A. ;
Chavan, Sachin ;
Crocella, Valentina ;
Howe, Joshua D. ;
Lee, Kyuho ;
Dzubak, Allison L. ;
Queen, Wendy L. ;
Zadrozny, Joseph M. ;
Geier, Stephen J. ;
Lin, Li-Chiang ;
Gagliardi, Laura ;
Smit, Berend ;
Neaton, Jeffrey B. ;
Bordiga, Silvia ;
Brown, Craig M. ;
Long, Jeffrey R. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (30) :10752-10761
[5]   Hydrocarbon Separations in a Metal-Organic Framework with Open Iron(II) Coordination Sites [J].
Bloch, Eric D. ;
Queen, Wendy L. ;
Krishna, Rajamani ;
Zadrozny, Joseph M. ;
Brown, Craig M. ;
Long, Jeffrey R. .
SCIENCE, 2012, 335 (6076) :1606-1610
[6]   Selective Binding of O2 over N2 in a Redox-Active Metal-Organic Framework with Open Iron(II) Coordination Sites [J].
Bloch, Eric D. ;
Murray, Leslie J. ;
Queen, Wendy L. ;
Chavan, Sachin ;
Maximoff, Sergey N. ;
Bigi, Julian P. ;
Krishna, Rajamani ;
Peterson, Vanessa K. ;
Grandjean, Fernande ;
Long, Gary J. ;
Smit, Berend ;
Bordiga, Silvia ;
Brown, Craig M. ;
Long, Jeffrey R. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (37) :14814-14822
[7]   Water Stability and Adsorption in Metal-Organic Frameworks [J].
Burtch, Nicholas C. ;
Jasuja, Himanshu ;
Walton, Krista S. .
CHEMICAL REVIEWS, 2014, 114 (20) :10575-10612
[8]   Microscopic origin of entropy-driven polymorphism in hybrid organic-inorganic perovskite materials [J].
Butler, Keith T. ;
Svane, Katrine ;
Kieslich, Gregor ;
Cheetham, Anthony K. ;
Walsh, Aron .
PHYSICAL REVIEW B, 2016, 94 (18)
[9]   Dramatic tuning of carbon dioxide uptake via metal substitution in a coordination polymer with cylindrical pores [J].
Caskey, Stephen R. ;
Wong-Foy, Antek G. ;
Matzger, Adam J. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (33) :10870-+
[10]   Formate modulated solvothermal synthesis of ZIF-8 investigated using time-resolved in situ X-ray diffraction and scanning electron microscopy [J].
Cravillon, Janosch ;
Schroeder, Christian A. ;
Bux, Helge ;
Rothkirch, Andre ;
Caro, Juergen ;
Wiebcke, Michael .
CRYSTENGCOMM, 2012, 14 (02) :492-498
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