Mosaic multistate scenario versus one-state description of supercooled liquids

被引:80
作者
Cavagna, Andrea
Grigera, Tomas S.
Verrocchio, Paolo
机构
[1] CNR, INFM, ISC, Inst Stat Mech & Complex, I-00185 Rome, Italy
[2] Natl Univ La Plata, INIFTA, RA-1900 La Plata, Argentina
[3] Natl Univ La Plata, Fac Ciencias Exactas, Dept Fis, RA-1900 La Plata, Argentina
[4] Consejo Nacl Invest Cient & Tecn, Buenos Aires, DF, Argentina
[5] Univ Trent, Dipartimento Fis, I-38050 Trento, Italy
[6] Univ Roma La Sapienza, CNR, INFM, SOFT, I-00185 Rome, Italy
[7] BIFI, Inst Biocomputac & Fis Sistemas Complejos, Zaragoza, Spain
关键词
D O I
10.1103/PhysRevLett.98.187801
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
According to the mosaic scenario, relaxation in supercooled liquids is ruled by two competing mechanisms: surface tension, opposing the creation of local excitations, and entropy, providing the drive to the configurational rearrangement of a given region. We test this scenario through numerical simulations well below the Mode Coupling temperature. For an equilibrated configuration, we freeze all the particles outside a sphere and study the thermodynamics of this sphere. The frozen environment acts as a pinning field. Measuring the overlap between the unpinned and pinned equilibrium configurations of the sphere, we can see whether it has switched to a different state. We do not find any clear evidence of the mosaic scenario. Rather, our results seem compatible with the existence of a single (liquid) state. However, we find evidence of a growing static correlation length, apparently unrelated to the mosaic one.
引用
收藏
页数:4
相关论文
共 30 条
  • [1] SOFT-SPHERE MODEL FOR THE GLASS-TRANSITION IN BINARY-ALLOYS - PAIR STRUCTURE AND SELF-DIFFUSION
    BERNU, B
    HANSEN, JP
    HIWATARI, Y
    PASTORE, G
    [J]. PHYSICAL REVIEW A, 1987, 36 (10) : 4891 - 4903
  • [2] Direct experimental evidence of a growing length scale accompanying the glass transition
    Berthier, L
    Biroli, G
    Bouchaud, JP
    Cipelletti, L
    El Masri, D
    L'Hôte, D
    Ladieu, F
    Pierno, M
    [J]. SCIENCE, 2005, 310 (5755) : 1797 - 1800
  • [3] Diverging length scale and upper critical dimension in the Mode-Coupling Theory of the glass transition
    Biroli, G
    Bouchaud, JP
    [J]. EUROPHYSICS LETTERS, 2004, 67 (01): : 21 - 27
  • [4] On the Adam-Gibbs-Kirkpatrick-Thirumalai-Wolynes scenario for the viscosity increase in glasses
    Bouchaud, JP
    Biroli, G
    [J]. JOURNAL OF CHEMICAL PHYSICS, 2004, 121 (15) : 7347 - 7354
  • [5] BRIGERA TS, 2004, PHYS REV B, V70
  • [6] CAMMAROTA C, 2006, THESIS U ROMA SAPIEN
  • [7] Spatially heterogeneous ages in glassy systems
    Castillo, HE
    Chamon, C
    Cugliandolo, LF
    Iguain, JL
    Kennett, MP
    [J]. PHYSICAL REVIEW B, 2003, 68 (13)
  • [8] Spatially heterogeneous dynamics in supercooled liquids
    Ediger, MD
    [J]. ANNUAL REVIEW OF PHYSICAL CHEMISTRY, 2000, 51 : 99 - 128
  • [9] Critical behavior of the specific heat in glass formers
    Fernández, LA
    Martín-Mayor, V
    Verrocchio, P
    [J]. PHYSICAL REVIEW E, 2006, 73 (02)
  • [10] Metastable states, relaxation times and free-energy barriers in finite-dimensional glassy systems
    Franz, S
    [J]. EUROPHYSICS LETTERS, 2006, 73 (04): : 492 - 498