Synthesis and structural characterization of Al4SiC4-homeotypic aluminum silicon oxycarbide, [Al4.4Si0.6][O1.0C2.0]C

A new quaternary layered oxycarbide, [Al439(5)Si0 (61(5))](Sigma 5)[O1 00(2)C2 00(2)](Sigma 3)C, has been synthesized and characterized by X-ray powder diffraction, transmission electron microscopy and energy dispersive X-ray spectroscopy (EDX). The title compound was found to be hexagonal with space group P6(3)/mmc, Z=2, and unit-cell dimensions a=0 32783(1)nm, c=2 16674(7)nm and V=0.20167(1)nm(3). The atom ratios Al Si were determined by EDX, and the initial structural model was derived by the direct methods. The final structural model showed the positional disordering of one of the three types of Al/Si sites The maximum-entropy methods-based pattern fitting (MPF) method was used to confirm the validity of the split-atom model, in which conventional structure bias caused by assuming intensity partitioning was minimized The reliability indices calculated from the MPF were R-wp=3 73% (S=1.20), R-p=2.94%, R-B = 1.04% and R-F =081% The crystal was an inversion twin Each twin-related individual was isostructural with Al4SIC4 (space group P6(3)mc, Z=2). (C) 2010 Elsevier Inc All rights reserved