Crystalingraphic characterization of (C5H4SiMe3)3U(BH4)

被引：2
作者：
Windorff, Cory J. [1 ,2 ,3 ]
Cross, Justin N. [1 ]
Scott, Brian L. [1 ]
Kozimor, Stosh A. [1 ]
Evans, William J. [2 ]
机构：
[1] Los Alamos Natl Lab, Los Alamos, NM 87544 USA
[2] Univ Calif Irvine, Dept Chem, Irvine, CA 92697 USA
[3] New Mexico State Univ, Dept Chem & Biochem, Las Cruces, NM 88003 USA
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2021年 / 77卷
关键词：
crystal structure; uranium; borohydride; cyclopentadienyl compounds; CRYSTAL-STRUCTURE; URANIUM; COMPLEXES; BOROHYDRIDE; TETRAHYDROBORATE; HYDRIDE;
D O I：
10.1107/S2056989021002425
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
New syntheses have been developed for the synthesis of (borohydrido-kappa H-3)tris[eta(5)- (trimethylsilyl)cyclopentadienyl]uranium (IV), [U(BH4)(C8H13Si)(3)] or Cp'U-3(BH4) (Cp' = C5H4SiMe3) and its structure has been determined by single-crystal X-ray crystallography. This compound crystallized in the space group P (1) over bar and the structure features three eta(5)-coordinated Cp' rings and a kappa(3)-coordinated (BH4)(-) ligand.
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页码：383 / +
页数：15
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