Preparation and Characterization of Samarium Doped Strontium Titanate

被引:0
|
作者
Huang Yongzhen [1 ,2 ]
Cheng Jigui [1 ]
Dong Jie
Xia Yonghong
机构
[1] Hefei Univ Technol, Sch Mat Sci & Engn, Hefei 230009, Peoples R China
[2] Anhui Vocat & Tech Coll, Hefei 230051, Peoples R China
关键词
samarium doped strontium titanate; gel-casting; phase composition; sinterability; electrical conductivity; OXIDE FUEL-CELLS; ANODES;
D O I
暂无
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Sr1-1.5xSmxTiO3 powders were prepared by gel-casting process. The effects of doping amount of samarium and sintering temperature on phase composition, sinterability and electrical conductivity of the Sr1-1.5xSmxTiO3 materials were investigated. The results showed that perovskite Sr1-1.5xSmxTiO3 powders can be obtained by calcining the dried gels at temperature above 1200 degrees C. Sintering temperature also has obvious influence on the densification of the Sr1-1.5xSmxTiO3 samples. Doping of samarium effectively improves the electrical conductivity of SrTiO3 samples. Electrical conductivity of the sintered Sr1-1.5xSmxTiO3 samples decreases as temperature increases from 500 to 850 degrees C. Maximum conductivity of 28.8 S.cm(-1) was achieved for Sr0.94Sm0.04TiO3 sample at 800 degrees C.
引用
收藏
页码:178 / 182
页数:5
相关论文
共 15 条
  • [1] Novel SOFC anodes for the direct electrochemical oxidation of hydrocarbon
    Gorte, RJ
    Kim, H
    Vohs, JM
    [J]. JOURNAL OF POWER SOURCES, 2002, 106 (1-2) : 10 - 15
  • [2] Production of nanotubes by the catalytic decomposition of different carbon-containing compounds
    Hernadi, K
    Fonseca, A
    Nagy, JB
    Siska, A
    Kiricsi, I
    [J]. APPLIED CATALYSIS A-GENERAL, 2000, 199 (02) : 245 - 255
  • [3] Effect of fabrication parameters on the electrical conductivity of YxSr1-xTiO3 for anode materials
    Huang, Xianliang
    Zhao, Hailei
    Shen, Wei
    Qiu, Weihua
    Wu, Weijiang
    [J]. JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2006, 67 (12) : 2609 - 2613
  • [4] Jenny M A, 1992, U.S. Patent, Patent No. [5,145,908, 5145908]
  • [5] A solid oxide fuel cell system fed with hydrogen sulfide and natural gas
    Lu, YX
    Schaefer, L
    [J]. JOURNAL OF POWER SOURCES, 2004, 135 (1-2) : 184 - 191
  • [6] MINH NQ, 1995, ELESVIER, P147
  • [7] EVALUATION OF THE EFFECTIVE REACTION ZONE AT NI(NIO)/ZIRCONIA ANODE BY USING AN ELECTRODE WITH A NOVEL STRUCTURE
    NAKAGAWA, N
    SAKURAI, H
    KONDO, K
    MORIMOTO, T
    HATANAKA, K
    KATO, K
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1995, 142 (10) : 3474 - 3479
  • [8] Chromite/titanate based perovskites for application as anodes in solid oxide fuel cells
    Pudmich, G
    Boukamp, BA
    Gonzalez-Cuenca, M
    Jungen, W
    Zipprich, W
    Tietz, F
    [J]. SOLID STATE IONICS, 2000, 135 (1-4) : 433 - 438
  • [9] QU SJ, 1994, ACTA PHYS CHIMICA SI, V10, P796
  • [10] SUN XF, 2006, ELECT SOURCE TECHNOL, V130, P282