Optical studies of the monolayer films of diazole-containing porphyrins at the air-water interface

被引：3
|
作者：
Ikeda, C [1 ]
Takashima, Y [1 ]
Irie, T [1 ]
Yoshioka, N [1 ]
Inoue, H [1 ]
机构：
[1] Keio Univ, Dept Appl Chem, Kohoku Ku, Yokohama, Kanagawa 2238522, Japan
来源：
MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 2000年 / 342卷
关键词：
porphyrin; pyrazole; imidazole; monolayer; coordination; supramolecular chemistry;
D O I：
10.1080/10587250008038248
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Optical properties of the monolayers of 5-(1-methylimidazol-2-yl)-10,15,20-tris(p-octyloxy- phenyl)porphyrin, 5-(1-methylpyrazol-4-yl)-10,15,20-tris(p-octyloxyphenyl)porphyrin and their zinc(II) complexes have been studied. The pi-A isotherms and UV-vis spectra have revealed that the zinc(II) complexes form coordination assemblies between peripheral nitrogen atom and central zinc(II) ion at the air-water interface with Very tight molecular packing.
引用
收藏
页码：81 / 86
页数：6
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