Self-assembled molecular ladders

被引：117

作者：

Fujita, M

Sasaki, O

Watanabe, KY

Ogura, K

Yamaguchi, K

机构：

[1] Chiba Univ, Fac Engn, Dept Appl Chem, Inage Ku, Chiba 263, Japan

[2] Chiba Univ, Ctr Chem Anal, Inage Ku, Chiba 263, Japan

来源：

NEW JOURNAL OF CHEMISTRY | 1998年 / 22卷 / 02期

关键词：

D O I：

10.1039/a708324f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Coordination of a pyridine-based bridging ligand, 1,4-bis(4-pyridylmethyl)benzene (1), with cadmium nitrate afforded an infinite ladder complex, the unit structure of which involves a T-shaped assembly of three pyridine rings about a heptacoordinated Cd-II atom. The ladder structure was found to expand its cavity volume by enclathrating p-dibromobenzene in the cavity. Nearly orthogonal interpenetration of infinite ladders was observed in the solid structure.

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页码：189 / 191

页数：3

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