Modification of gelatin by reaction with 1,6-diisocyanatohexane

被引：28

作者：

Bertoldo, Monica ^{[1
]}

Bronco, Simona ^{[1
]}

Gragnoli, Tania ^{[1
]}

Ciardelli, Francesco ^{[1
]}

机构：

[1] Univ Pisa, Dipartimento Chim & Chim Ind, PolyLab, CNR, I-56126 Pisa, Italy

来源：

MACROMOLECULAR BIOSCIENCE | 2007年 / 7卷 / 03期

关键词：

crosslinked gelatin; gels; isocyanates; textile fibers;

D O I：

10.1002/mabi.200600215

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

1,6-Diisocyanatohexane and dimethyl sulfoxide were exploited as crosslinking agent and reaction solvent, respectively, for gelatin modification. Crosslinked samples were fractionated and analyzed by thermogravimetric analysis, infrared spectroscopy, acid and base titrations, and swelling measurements. The yield of crosslinking was found to increase with increasing diisocyanate and gelatin concentrations and the amount of bound crosslinker was evaluated. The chemical analysis of the reaction products allowed the process parameters to be related to the properties of the textile/ gelatin composites. For this purpose poly(propylene)-, poly(ethylene terephthalate)-, and cotton-based textiles were treated to prepare soft and dimensionally stable supported materials with a gel phase composed of gelatin.

引用

页码：328 / 338

页数：11

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