CO2 removal using membrane gas absorption

The objective of this study is to investigate the potential process for the removal of carbon dioxide (CO2) from flue gas using fundamental membrane contactor, which is a membrane gas absorption (MGA) system. The experiments consisted of microporous polyvinylidenefluoride (PVDF) flat sheet membrane with 0.1 mu m (as module I) and 0.45 mu m (as module II) pore size. 2-Amino-2-methyl-1-propanol (AMP) solution was employed as the liquid absorbent. The effect of AMP concentration was studied with variation in the range 1-5 M. In addition, the experiments were carried out with 10%, 20%, 30% and 40% gas ratio of CO2 to N-2 and pure CO2 as well. Through contact angle measurement, membranes for module I and module II were obtained with CA values of around 130.25 degrees and 127.77 degrees, respectively. The mass transfer coefficients for module II are lower than those of module I for 1-5 M of AMP. Furthermore, the increase in CO2 concentration in the feed gas stream enhanced the CO2 flux as the driving force of the system was increased in sequence from 1 M to 5 M of AMP. However, after the particular percentage (40%) of CO2 inlet concentration, the CO2 fluxes seem saturated. The combination of AMP as liquid absorbent and PVDF microporous membrane in MGA system has shown the potential to remove the CO2 from flue gas. In addition, the higher AMP concentration gave higher mass transfer coefficient at low liquid flow rates. (C) 2009 Elsevier Ltd. All rights reserved.