The first unambiguous determination of a nitrosyl-to-nitrite conversion in an iron nitrosyl porphyrin

被引：53
作者：
Cheng, L
Powell, DR
Khan, MA
Richter-Addo, GB
机构：
[1] Univ Oklahoma, Dept Chem & Biochem, Norman, OK 73019 USA
[2] Univ Wisconsin, Dept Chem, Xray Struct Lab, Madison, WI 53706 USA
来源：
CHEMICAL COMMUNICATIONS | 2000年 / 23期
关键词：
D O I：
10.1039/b006775j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The picket fence porphyrin complex [Fe(tpivpp)(NO)] undergoes complete conversion to the isolable N-bound nitrite derivative [Fe(tpivpp)(NO2)(py)] in air in the presence of pyridine: reconversion to the starting nitrosyl complex is achieved using triphenylphosphine as reductant.
引用
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页码：2301 / 2302
页数：2
相关论文
共 14 条
[1]  
CHENG L, 2000, PORPHYRIN HDB, pCH33
[2]   PICKET-FENCE PORPHYRINS - SYNTHETIC MODELS FOR OXYGEN BINDING HEMOPROTEINS [J].
COLLMAN, JP ;
GAGNE, RR ;
REED, CA ;
HALBERT, TR ;
LANG, G ;
ROBINSON, WT .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (06) :1427-1439
[3]   Syntheses, characterization, and structural studies of several (Nitro)(nitrosyl)iron(III) porphyrinates:: [Fe(Porph)(NO2)(NO)] [J].
Ellison, MK ;
Schulz, CE ;
Scheidt, WR .
INORGANIC CHEMISTRY, 1999, 38 (01) :100-108
[4]   ELECTROCHEMISTRY OF NITRITE REDUCTASE MODEL COMPOUNDS .2. FORMATION OF AN IRON BIS-NITRO PORPHYRIN COMPLEX [J].
FERNANDES, JB ;
FENG, DW ;
CHANG, A ;
KEYSER, A ;
RYAN, MD .
INORGANIC CHEMISTRY, 1986, 25 (15) :2606-2610
[5]   INSTABILITY OF THE NITRITE IRON(III) PORPHYRINATE SYSTEM [J].
FINNEGAN, MG ;
LAPPIN, AG ;
SCHEIDT, WR .
INORGANIC CHEMISTRY, 1990, 29 (02) :181-185
[6]   6-COORDINATE QUANTUM-MECHANICALLY WEAKLY SPIN-MIXED (S = 5/2, 3/2) (TRIFLATO)AQUOIRON(III) PICKET-FENCE PORPHYRIN COMPLEX - SYNTHESIS AND STRUCTURAL, MOSSBAUER, EPR, AND MAGNETIC CHARACTERIZATION [J].
GISMELSEED, A ;
BOMINAAR, EL ;
BILL, E ;
TRAUTWEIN, AX ;
WINKLER, H ;
NASRI, H ;
DOPPELT, P ;
MANDON, D ;
FISCHER, J ;
WEISS, R .
INORGANIC CHEMISTRY, 1990, 29 (15) :2741-2749
[7]  
Kurtikyan TS, 1999, RUSS J COORD CHEM+, V25, P28
[8]   Reactivity of the iron porphyrin Fe(TPP)(NO) with excess NO.: Formation of Fe(TPP)(NO)(NO2) occurs via reaction with trace NO2 [J].
Lorkovic, IM ;
Ford, PC .
INORGANIC CHEMISTRY, 2000, 39 (04) :632-+
[9]   (Nitro)iron(III) porphyrins. EPR detection of a transient low-spin iron(III) complex and structural characterization of an O atom transfer product [J].
Munro, OQ ;
Scheidt, WR .
INORGANIC CHEMISTRY, 1998, 37 (09) :2308-2316
[10]   REACTIONS OF BIS(NITRO) ALPHA,ALPHA,ALPHA,ALPHA-TETRAKIS(ORTHO-PIVALAMIDOPHENYL)PORPHINATO)FERRATE(III) WITH PYRIDINE AND IMIDAZOLE - EPR AND MOSSBAUER-SPECTRA AND MOLECULAR-STRUCTURES OF THE MIXED-LIGAND SPECIES [J].
NASRI, H ;
WANG, YN ;
HUYNH, BH ;
WALKER, FA ;
SCHEIDT, WR .
INORGANIC CHEMISTRY, 1991, 30 (07) :1483-1489
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