Non-innocent ligands in bioinorganic chemistry-An overview

被引：482

作者：

Kaim, Wolfgang ^{[1
]}

Schwederski, Brigitte ^{[1
]}

机构：

[1] Univ Stuttgart, Inst Anorgan Chem, D-70569 Stuttgart, Germany

来源：

COORDINATION CHEMISTRY REVIEWS | 2010年 / 254卷 / 13-14期

关键词：

Bioinorganic chemistry; Nitrosyl complexes; Non-innocent ligands; Porphyrins; Quinones; PHOTOSYNTHETIC REACTION CENTERS; TRANSITION-METAL-COMPLEXES; IRON-OXYGEN BOND; COORDINATION CHEMISTRY; ELECTRONIC-STRUCTURE; RHODOBACTER-SPHAEROIDES; INTRADIOL DIOXYGENASES; CRYSTAL-STRUCTURE; REDOX REACTIVITY; NITRIC-OXIDE;

D O I：

10.1016/j.ccr.2010.01.009

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This review touches the most common instances where non-innocent ("suspect") behaviour of redoxactive ligands, either substrates or supporting components, is observed in a biochemical context. These ligands include the O-2/O-2(center dot-)/O-2(2-), NO+/NO center dot/NO-, o-quinone/o-semiquinone/catecholate and tyrosyl/tyrosinate reclox systems, the tetrapyrrole (porphyrinic) ligands, the pterins and flavins, and the dithiolene/ene-dithiolate ligands in molybdo- and tungstopterin. These non-innocent ligands are discussed in their interaction with biological iron, copper, manganese, molybdenum or tungsten centers. (C) 2010 Elsevier B.V. All rights reserved.

引用

页码：1580 / 1588

页数：9

共 118 条

[1] Dopamine complexes of iron in the etiology and pathogenesis of Parkinson's disease [J].

Arreguin, Shelly ;

Nelson, Paul ;

Padway, Shelby ;

Shirazi, Matthew ;

Pierpont, Cortlandt .

JOURNAL OF INORGANIC BIOCHEMISTRY, 2009, 103 (01) :87-93

[2] Oxidation states, atomic charges and orbital populations in transition metal complexes [J].

Aullon, Gabriel ;

Alvarez, Santiago .

THEORETICAL CHEMISTRY ACCOUNTS, 2009, 123 (1-2) :67-73

[3] OXIDATION OF ORTHO-QUINONE ADDUCTS OF TRANSITION-METAL COMPLEXES [J].

BALCH, AL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1973, 95 (08) :2723-2724

[4]

Banerjee R., 2008, Redox Chemistry

[5] Structural systematics for o-C6H4XY ligands with X,Y= O, NH, and S donor atoms.: o-Iminoquinone and o-iminothioquinone complexes of ruthenium and osmium [J].

Bhattacharya, S ;

Gupta, P ;

Basuli, F ;

Pierpont, CG .

INORGANIC CHEMISTRY, 2002, 41 (22) :5810-5816

[6] Mechanism for catechol ring cleavage by non-heme iron intradiol dioxygenases: A hybrid DFT study [J].

Borowski, Tomasz ;

Siegbahn, Per E. M. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (39) :12941-12953

[7] Copper-containing amine oxidases. Biogenesis and catalysis; a structural perspective [J].

Brazeau, BJ ;

Johnson, BJ ;

Wilmot, CM .

ARCHIVES OF BIOCHEMISTRY AND BIOPHYSICS, 2004, 428 (01) :22-31

[8] BINDING-SITES OF QUINONES IN PHOTOSYNTHETIC BACTERIAL REACTION CENTERS INVESTIGATED BY LIGHT-INDUCED FTIR DIFFERENCE SPECTROSCOPY - SYMMETRY OF THE CARBONYL INTERACTIONS AND CLOSE EQUIVALENCE OF THE Q(B) VIBRATIONS IN RHODOBACTER-SPHAEROIDES AND RHODOPSEUDOMONAS-VIRIDIS PROBED BY ISOTOPE LABELING [J].

BRETON, J ;

BOULLAIS, C ;

BERGER, G ;

MIOSKOWSKI, C ;

NABEDRYK, E .

BIOCHEMISTRY, 1995, 34 (36) :11606-11616

[9] MECHANISMS OF FLAVIN CATALYSIS [J].

BRUICE, TC .

ACCOUNTS OF CHEMICAL RESEARCH, 1980, 13 (08) :256-262

[10] Non-heme iron-dependent dioxygenases: unravelling catalytic mechanisms for complex enzymatic oxidations [J].

Bugg, Timothy D. H. ;

Ramaswamy, S. .

CURRENT OPINION IN CHEMICAL BIOLOGY, 2008, 12 (02) :134-140

← 1 2 3 4 5 6 7 8 9 10 →